AgCo bimetallic cocatalyst modified g-C3N4 for improving photocatalytic hydrogen evolution
Bimetallic AgCo/g-C 3 N 4 photocatalysts were successfully prepared by a facile chemical reduction method and used to investigate their photocatalytic H 2 production performance. Bimetallic AgCo as a cocatalyst can be well matched with g-C 3 N 4 , which is beneficial for increasing the number of active reaction sites and narrowing the band gap. A possible photocatalytic mechanism was explored by XRD , FTIR, SEM, TEM, UV–vis DRS , BET, and PL characterization. The photocatalytic H 2 production activity of the optimal 5%AgCo/g-C 3 N 4 photocatalyst reached 12994.2 μmoL/g, which was 54.7 times higher than g-C 3 N 4 . Owing to the close interfacial contact between bimetallic AgCo and g-C 3 N 4 , the transfer distance was shortened, and the photogenerated electron and hole pairs were effectively separated. This study provides a new strategy for the synthesis of excellent H 2 production photocatalysts using bimetallic nanoparticles .
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