Ultrasound-Assisted Hydrothermal Fabrication of AgI/MFeO3/g-C3N4 (M = Y, Gd, La) Nano Sheet–Sphere–Sheet Photocatalysts with Enhanced Photodegradation Activities for Norfloxacin
AgI/MFeO3/g-C3N4(M = Y, Gd, La) nano sheet–sphere–sheet photocatalysts were synthesized by a simple ultrasound-assisted hydrothermal approach. We characterized the microstructure, surface morphology, and optical absorption capacity of the obtained samples. According to the characterization results, AgI/MFeO3/g-C3N4(M = Y, Gd, La) nano sheet–sphere–sheet photocatalysts were successfully obtained. MFeO3nanospheres and AgI nanosheets were dispersed evenly on the surface of g-C3N4nanosheets. AgI/MFeO3/g-C3N4showed remarkable photocatalytic. Especially, 95% of NOF was photodegradated over AgI/LaFeO3/g-C3N4within 3 h and the higher photocatalytic performance still remained after six cycles. Additionally, The N2adsorption–desorption isotherms of AgI/MFeO3/g-C3N4showed that AgI/LaFeO3/g-C3N4possessed the highest specific surface area (79.32 m2/g). The result of scavenging experiment revealed that ·O2−, h+, and ·OH were the main roles in the photodegradation process. Benefitting from the nice energy band matching, MFeO3acted as the center of photogenerated electrons migration and separation provided more direct electron channels. This work proposes an effective approach for the design and configuration of dual Z-scheme photocatalysts to accomplish the removal of organic contaminants based on g-C3N4.
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