Dual photothermal-photocatalytic Au@ZIF-8/Ti3C2Tx nanocomposite for enhanced solar steam sterilization and biofouling-resistant hydrogel membrane
Solar-driven interfacial water evaporation holds great promise for water purification and desalination, but challenges such as insufficient light absorption, suboptimal energy conversion, and microbial contamination hinder its practical applications. This study presents a novel Au@ZIF-8/Ti 3 C 2 T x alginate hydrogel, integrating nanocomposites into a three-dimensional hydrogel network to enhance both water transport and light-to-heat conversion. The incorporation of Au nanoparticles significantly improves light absorption, while the Schottky junction between ZIF-8 and Ti 3 C 2 T x promotes photocatalytic generation of reactive oxygen species (ROS), including superoxide radicals (O 2 − ) and singlet oxygen ( 1 O 2 ). This photocatalytic activity, combined with the photothermal effects of Ti 3 C 2 T x , leads to effective bacterial sterilization, achieving 99.54 % and 97.22 % antibacterial efficiency against E. coli and S. aureus , respectively. The hydrogel exhibits a high evaporation rate of 1.589 kg m −2 h −1 and demonstrates a 100 % steam sterilization rate against both bacterial strains under one sun illumination. These findings highlight the potential of the Au@ZIF-8/Ti 3 C 2 T x alginate hydrogel as a promising, efficient, and cost-effective sterilization strategy for various applications, including water purification, desalination, and disinfection in off-grid areas and specialized settings.
危险品化学品经营许可证（带存储）