Optimization of Zn2GeO4 microwave dielectric ceramics via Cu substitution and B2O3 sintering aid for LTCC application
A series of Zn 2- x Cu x GeO 4 ceramics were prepared by the solid-phase sintering method. Cu 2+ substitution for Zn 2+ facilitated the single-phase formation and benefited densification via lowering the sintering temperatures , hence thereby the microwave dielectric properties were largely improved. A representative composition with x = 0.08 revealed a homogenous Zn 2 GeO 4 phase with good microwave dielectric properties: ε r ∼ 7.47, Q × f ∼ 56,980 GHz, and τ f ∼ −13.9 ppm/°C when sintered at 1000 °C. To evaluate the potential application of low-temperature cofired ceramics (LTCC), sintering aids (B 2 O 3 ) were added to the x = 0.08 sample to reduce its sintering temperature to below 960 °C. A dramatic improvement in Q × f ∼ 107,415 GHz was observed with only 0.5 wt % B 2 O 3 addition. Chemical compatibility was confirmed via cofiring with silver electrodes at 940 °C. All the merits show promising potential for advanced substrates.
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