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International Journal of Applied Ceramic Technology · 2022 ·Vol. 20 ·期 2 ·906-916 · IF 2.328

B2O3-modified geopolymer and its liquid-phase sintered products for immobilization of strontium

Lingyu Jia,Peigang He,Dechang Jia,Jingkun Yuan,Delong Cai,Daxin Li,Xiaoming Duan,Zhihua Yang,Yu Zhou

Sr-containing ceramic products produced from geopolymer, (Na, Sr)-GP, have been reported as excellent candidate materials for the immobilization of radionuclide 90Sr, despite sintering temperature at 1200°C. In this work, the product possessing the best immobilization performance (leaching rate of 1.29% for Sr 2+ ) can be produced at 1000°C in the method of liquid-phase sintering via the addition of fluxing agent B 2 O 3 at 2.0 wt% in the geopolymer precursor. The mechanical properties of the geopolymer precursor (Na, Sr)-GP were also enhanced via the promotion role of B 2 O 3 to geopolymerization. It was revealed that the overall anti-leaching ability of the Sr-containing ceramic product not only depends on the microstructure of the loading substrate but also can be affected by the chemical state of radioactive strontium retention in the loading matrix.

研究领域: 材料科学 · 环境科学
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