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ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES · 2016 ·Vol. 71 ·期 8 ·869-874 · IF 0.686

Syntheses, crystal structures, and characterization of two Mn(II) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

Gao-Feng Wang,Xiao Zhang,Shu-Wen Sun,Hong Sun,Xia Yang,Hui Li,Chen-Zhong Yao,Shu-Gang Sun,Yu-Peng Tang,Li-Xin Meng

Two Mn(II) complexes, {[Mn(BIPMO) 2 Cl 2 ] · 2(H 2 O)} n ( 1 ) and {[Mn(BIPMO) 2 (SCN) 2 ] · 2(CH 3 OH)} n ( 2 ) (BIPMO = bis(4-(1 H -imidazol-1-yl)phenyl)methanone) with V-shaped BIPMO ligands, were synthesized and characterized by IR spectroscopy and elemental analyses along with their single-crystal X-ray diffraction analyses. The Mn(II) ions in 1 and 2 are both six-coordinated to four nitrogen atoms of four BIPMO ligands and two anions (Cl − for 1 , and SCN − for 2 ) to form a distorted octahedral geometry.

CAS / MDL: 1762-95-4 13446-34-9

研究领域: 配位化学 · 晶体学

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JOURNAL OF STRUCTURAL CHEMISTRY · 2018 ·Vol. 59 ·期 3 ·744-747 · IF 0.521

Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands

Sun S.-W.,Wang G.-F.

The synthesis of a novel Cu(I) complex with V-shaped bidentate ligands {[Cu(BIPMO)]×[CuBr 2 ]} n where BIPMO = bis(4-(1 H -imidazol-1-yl)phenyl)methanone is reported. It is characterized by IR spectroscopy, elemental analysis, and single crystal X-ray diffraction. Copper(I) ions in the complex are in a distorted environment in which donor atoms are provided by the bromide anion and nitrogen atoms of BIPMO ligands, respectively. Infinite anion chains formed by CuX 4 (X = Br or N) polyhedra are linked by BIPMO ligands to give rise to layers. Furthermore, the layers are linked into 3D networks through weak intermolecular interactions.

研究领域: 无机化学 · 材料科学 · 晶体学

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Syntheses, crystal structures, and characterization of two Mn(II) coordination polymers with bis(4-(1H-imidazol-1-yl)phenyl)methanone ligands

Structural Characterization of a Cu(I)/Br Complex with Bis(4-(1H-Imidazol-1-Yl)Phenyl)Methanone Ligands