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BTA/PPy/MIL-88(Fe)
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY · 2022 · IF 6.76

Dual-inhibitor composite BTA/PPy/MIL-88(Fe) for active anticorrosion of epoxy resin coatings

Meng Zhang,Yu Zhang,Yucong Chen,Xiaoru Tian,Lingzhi Liu,Yizhong Wang,Ruijie Guo,Hong Yan

MIL-88(Fe) was used as an oxidant and a hard template for the synthesis of polypyrrole (PPy) on its surface, and the formation of PPy made the surface of MIL-88(Fe) rougher as well as more voids formed in the interior. The increased specific surface area allowed more benzotriazole (BTA) (17.8 wt%) loaded on PPy/MIL-88 particles. BTA/PPy/MIL-88(Fe) was employed as a novel corrosion inhibitor to enhance the corrosion resistance of epoxy coating for carbon steel. BTA/PPy/MIL-88(Fe) filler improved the corrosion resistance of EP coating without/with artificial scratch by delaying the cathodic and anodic reactions in corrosive media. Both BTA and MIL-88(Fe) played the role of corrosion inhibitors, making EP coating possess active corrosion protection and pH-sensitive performance. Besides, BTA/PPy/MIL-88(Fe) enhanced the adhesion of EP coating by filling the pores inside.

研究领域: 材料科学 · 防腐蚀工程 · 化学工程
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