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Bi/TiO2/WO3·0.33H2O
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS · 2020 ·Vol. 31 ·期 14 ·11276-11285 · IF 2.22

Synthesis of Z-scheme Bi/TiO2/WO3·0.33H2O heterojunction material for the enhanced photocatalytic degradation of pollutants

Deng Yuehong,Zhou Yi,Tang Haiqin,Xu Yifeng,Tan Yawen,Zou Hao,Xiang Ye

In this work, Bi spheres were deposited on bulk WO 3 ·0.33H 2 O and TiO 2 (P25) nanoparticles to form Z-scheme Bi/TiO 2 /WO 3 ·0.33H 2 O heterojunction material for the first time by a simple hydrothermal method. The as-prepared materials were comprehensively characterized by XRD, XPS, SEM, TEM, UV–Vis DRS, BET surface area, EIS, and Mott-Schottky analysis. The ternary Bi/TiO 2 /WO 3 ·0.33H 2 O composites exhibited superior degradation efficiency for RhB than pure WO 3 ·0.33H 2 O, TiO 2 (P25), and their binary composites. The degradation rate reached 99.84% after 30 min under simulated sunlight. The enhancement of photocatalytic activity could be attributed to the Z-scheme heterojunction system with metal Bi as an electronic medium, which greatly enhanced the efficiency of charge separation. This report demonstrated that Z-scheme Bi/TiO 2 /WO 3 ·0.33H 2 O heterojunction photocatalytic material has potential application value in dye wastewater treatment.

研究领域: 材料科学 · 环境科学 · 化学工程
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