A highly conductive Ce0.8Nd0.2O1.9 electrolyte with double sintering aids for intermediate-temperature solid oxide fuel cells
In this paper, the influence of Bi/Zn mass ratio on the phase composition, microstructure, sintering properties, and electrical properties of Bi/Zn co-added Nd 0.2 Ce 0.8 O 1.9 (NDC) used for intermediate-temperature solid oxide fuel cells (SOFCs) was investigated. At 700 °C, the total conductivity of the NDC-based electrolyte (3Bi/1Zn-NDC) with the mass ratio 3:1 for Bi 2 O 3 and ZnO was as high as 5.89 × 10 −2 S cm −1 , 4.60 and 4.51 times higher than the single addition of 4 wt% Bi 2 O 3 and 4 wt% ZnO, respectively. In addition, the 3Bi/1Zn-NDC electrolyte exhibited a good physical and chemical compatibility with the electrode materials. The open circuit voltage (OCV) of the cell supported by the 3Bi/1Zn-NDC electrolyte was 0.67 V, and the output power density could reach 402.25 mW cm −2 at 700 °C. It showed stable power output and OCV in the long-term stability test within 50 h. Overall, the combination of 3 wt% Bi 2 O 3 and 1 wt% ZnO was a very effective dual sintering aid for NDC electrolyte.
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