Template-Assisted Synthesis of Dy3+-Doped Bi2SiO5 Nanospheres with Excellent Luminescence and Thermal Stability
In this work, Dy 3+ -doped Bi 2 SiO 5 nanoparticles with uniform spherical morphology and narrow size distribution have been successfully synthesized using a facile template-assisted approach. The effects of sintering temperature and Dy 3+ doping concentration on the phase composition, morphology, and luminescence properties of Bi 2 SiO 5 :Dy 3+ nanophosphor are systematically investigated through X-ray diffraction, scanning electron microscopy, and photoluminescence (PL) spectroscopy. X-ray diffraction results confirm that the synthesized Bi 2 SiO 5 :Dy 3+ nanospheres exhibit a pure tetragonal phase. Meanwhile, the phosphor particles are composed of monodisperse nanospheres with an average diameter of approximately 265 nm. Upon excitation at 388 nm, intense photoluminescence is noted in the blue ( 4 F 9/2 → 6 H 15/2 ) and yellow ( 4 F 9/2 → 6 H 13/2 ) spectral regions due to the characteristic emissions of Dy 3+ ions. Temperature-dependent PL spectra reveal that the optimized Bi 2 SiO 5 :2.5%Dy 3+ nanospheres maintain extraordinary luminescence thermal stability, retaining 81.0% of its emission intensity at 423 K compared to 303 K. The phosphor also showed remarkable color stability, with CIE chromaticity coordinates shifting minimally from (0.377, 0.413) at 303 K to (0.373, 0.407) at 423 K. This newly developed Bi 2 SiO 5 :Dy 3+ nanospheres exhibit commendable PL properties, enabling them as promising candidates for yellow phosphors in LEDs and display applications.
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