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RSC Advances · 2015 ·Vol. 5 ·期 85 ·69854-69860 · IF 3.84

Facile thermal annealing of graphite oxide in air for graphene with a higher C/O ratio

Suyun Tian,Jing Sun,Siwei Yang,Peng He,Shengju Ding,Guqiao Ding,Xiaoming Xie

Rapid thermal exfoliation/reduction of graphite oxide is a fast and easy method among the oxidation–reduction approaches for graphene synthesis. In this research, we firstly demonstrated that graphene can be obtained with a surface area of 550 to 700 m2 g−1 and a yield of approximately 50% through one-step rapid thermal treatment in air from 450 to 550 °C, without vacuum or protective gas through a self-protection process. Then, we further demonstrated the effective two-step thermal annealing to significantly improve the C/O ratio from ca. 7.3 to 25.9 in air at the relatively low temperature of 600 °C. The smart self-protecting and enhanced-oxygen-removal mechanisms were discussed.

研究领域: 材料科学 · 化学工程
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