Enhancing electromagnetic wave absorption performance of one-dimensional C@Co/N-doped C@PPy composite fibers
Electrospinning is one of the attractive technologies for fabrication carbon-based fibers due to its high efficiency, component controllability and functionalities. Here, a multi-step strategy was used for the efficient synthesis of one-dimensional (1D) MOF-derived C@Co/N-doped carbon@polypyrrole (C@Co/NC@PPy) composite fibers . The composite fibers synthesized by introducing the electrospinning method possessed unique structural anisotropy and multiple absorption mechanisms. The electromagnetic parameters , the absorption performance and the internal mechanisms of samples were thoroughly illustrated. By adjusting the filler loadings of samples, the electromagnetic wave (EMW) absorption could be optimized. The C@Co/NC@PPy with 35 wt% filler loading showed the optimal performance. Impressively, with a thickness of merely 1.65 mm, the C@Co/NC@PPy composite fibers delivered high performance with the minimum reflection loss (RL min ) of -72.14 dB. Correspondingly, the maximum effective absorption bandwidth (EAB max ) could reach 5.6 GHz with the thickness of 1.88 mm. Furthermore, the 35 wt% loading C@Co/NC@PPy composite fibers could reach 14.28 GHz (89.25% of 2–18 GHz) effective absorption, showing the ultrawide absorption. Those positive results forcefully verified that the 1D MOF-derived C@Co/NC@PPy composites showed great potential and superiority as EMW absorption material .
危险品化学品经营许可证（带存储）