Ru-Catalyzed ortho-Selective Diborylation of 2-Arylpyridines toward the Construction of π-Conjugated Functions
A ruthenium catalytic ortho-C–H diborylation of 2-arylpyridine derivatives, including challenging 2-phenoxypyridine functions, using a remarkably low catalyst loading and a low-cost and bench-stable boron source, has been developed. The novel strategy shows high activity with excellent selectivity and may offer a versatile and green alternative to currently employed high loadings of noble metals or extra additives for the selective borylations.
研究领域:
有机化学
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催化化学
✓ 已验证
DOI
高影响因子
危险品化学品经营许可证（带存储）