Miniature spectrometer is powerful tool for scientific research and industrial inspection. Here, we report the fabrication of graded perovskite filters with tunable bandgap and their application in constructing miniature spectrometer. The graded perovskite filters were fabricated using a Finkelstein reaction between in-situ formed halogen ion with a preformed MAPbX 3 film. The graded bandgap of perovskite films can be well tunned from 400 to 750 nm by controlling the volume ratio between 5,5-dimethyl-1-pyrroline N -oxide and benzyl chloride(bromide). By combining a deep residual network, graded bandgap perovskite film and commercial CMOS sensor chip, a miniature spectrometer is demonstrated, achieving an accurate spectrum reconstruction (PSNR = 40.749) with monochromatic spectral resolution of 1.31 nm.
Biological visions have inspired the development of artificial vision systems with diverse visual functional traits, however, the detected wavelength is only in visible light between 0.4 and 0.78 μm, restricting their applications. Snakes generate a thermal image of animals due to pit organs for detecting and converting infrared, allowing them to accurately target predators or prey even under darkness. Inspired by natural infrared visualized snakes, we propose artificial vision systems with CMOS sensors-integrated upconverters to break visible light limitations to realize 3840 × 2160 ultra-high-resolution short-wave infrared (SWIR) and mid-wave infrared (MWIR) visualization imaging for the first time. Through colloidal quantum dot barrier heterojunction architecture design of infrared detecting units and the introduction of co-hosted emitting units, the luminance and upconversion efficiency reach up to 6388.09 cd m −2 and 6.41% for SWIR, 1311.64 cd m −2 and 4.06% for MWIR at room temperature. Our artificial vision systems broaden a wide spectrum of applications within infrared, such as night vision, agricultural science, and industry inspection, marking a significant advance in bioartificial vision.
危险品化学品经营许可证（带存储）