Materials Today Chemistry
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2022
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IF 7.613
Tian Xia,Zhuangzhuang Wu,Ying Liang,Wenxin Wang,Yongpeng Li,Zhuyin Sui,Linlin Shan,Chaokun Li,Ruimei Fan,Qi Chen
The design and fabrication of versatile covalent organic frameworks (COFs) with multiple properties for diverse applications is highly desirable. Here, the difunctional COFs material g–C 18 N 3 –COF was prepared and modified to be applied for efficient photocatalytic degradation of Rhodamine B (RhB) and pH detection, respectively. Owing to the triazine unit which was suitable for photocatalyst construction, g–C 18 N 3 –COF was sensitive to visible light and exhibited excellent photocatalysis capability toward RhB. Specially, the photocatalytic degradation of RhB with a high concentration of 300 ppm using g–C 18 N 3 –COF reached equilibrium within 6 h. Moreover, g–C 18 N 3 –COF was further grown in-situ onto the filter paper to generate a novel composite material g–C 18 N 3 –COF@Paper with bright yellow fluorescence. g–C 18 N 3 –COF@Paper could visualize the pH detection by remarkable changes in its fluorescent intensity and color in the range of pH value from 1 to 5, on account of the protonation of the nitrogen atoms from the triazine ring in g–C 18 N 3 –COF. The triazine-based sp 2 carbon-conjugated g–C 18 N 3 –COF, respectively, used as photocatalyst and sensor in this work offers a new strategy to construct the versatile COFs material, facilitating the application of functional COFs in the environmental protection field.
研究领域:
材料科学
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环境科学
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化学工程
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DOI
高影响因子
Water
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2021
·Vol. 13
·期 23
·3338
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IF 3.103
Yunjie Ma,Xin Gao,Yang Ruan,Hang Cui,Li Zhang,Wei Zhang,Shaoyan Wang
Resin based covalent organic framework material was used as filler for solid phase extraction (SPE), and the solid phase extraction effect was compared with that of traditional COF material (TpBD COFs). The enrichment capacity of four phthalate esters (dimethyl phthalate, diethyl phthalate, dibutyl phthalate, dioctyl phthalate) in beverage samples was investigated by SPE. Adsorption experiments showed that the kinetic adsorption behavior of COF materials for phthalate esters (PAEs) was more consistent with the quasi-second-order kinetic adsorption model, and the static adsorption behavior is more in line with the Freundlich isothermal adsorption model. Solid phase extraction experiments proved that the SPE column prepared with two COF materials as adsorbents had good adsorption effects, high recovery (water: 97.99–100.56% and beverage: 97.93–100.23%) and were reusable (50 cycles), which could meet the requirements for trace detection of phthalate ester. It was found that the solid phase extraction effect was better than the four types of commercial SPE columns. The new COF material reduced the cost of monomer use and provided the possibility for its industrial production. Meanwhile, it also provided a new feasible scheme for enriching trace phthalate esters in practical samples.Keywords:resin-based COFs;phthalate esters;solid phase extraction;trace analysis
研究领域:
分析化学
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环境科学
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DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2019
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IF 8.355
Guiliang Li,Jianrong Ye,Qile Fang,Fu Liu
Covalent organic frameworks (COFs) materials with designed skeleton structure and controlled pore size are a new class of adsorbent materials for environment remediation. Here, we synthesize two amide-based COFs materials via a polymerization reaction of acyl chloride and amino groups by mechanical ball milling at room temperature for Pb 2+ removal as adsorbents. Two types of diamine monomers are selected to construct COFs with different framework structure and functional groups contents, i.e. COF-TP from aromatic diamine and COF-TE from linear diamine. The as-prepared COFs materials display typical lamellar structure, and the amide groups on COFs skeleton are confirmed to behave as active adsorption sites for Pb 2+ capture via multi-coordination. COF-TE exhibits superior Pb 2+ adsorption capacity to COF-TP, because that less aromatic skeleton and weak π-π stacking of COF-TE facilitate higher internal diffusion of Pb 2+ adsorption. Meanwhile, the higher amide group content on COF-TE leads to its higher saturated adsorption capacity of 185.7 mg/g than COF-TP of 140.0 mg/g. Finally, great recycling stability of Pb 2+ adsorption allows the amide-based COFs materials to be promising adsorbents for heavy metal Pb 2+ removal or recovery.
研究领域:
环境科学
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材料科学
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DOI
高影响因子
MICROCHEMICAL JOURNAL
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2025
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IF 5.1
Xiuzhen Li,Yuanting Ni,Chenxi Liu,Shaohua Xu,Wei Shu,Hong Liang,Ming Chen
Background Homocysteine (Hcy) has been recognized as an independent risk factor for the development of cardiovascular disease. Many electrochemical detection methods have been developed for analyzing Hcy, however, the specificity of these methods is based on the interaction between the sulfhydryl groups in Hcy and the metallic materials, and thus the specificity of such detection is not satisfactory. Results In this study, an electrochemical sensor based on COFs and Pd@CuO was developed for the specific detection of Hcy. Firstly, COFs material was used as an immobilized carrier for cystathionine β-synthase (CBS), and the immobilized CBS as a recognition unit was able to catalyze the production of H 2 S from the substrates (Hcy and Cys) in a specific manner. Secondly, the Pd@CuO composite material has excellent conductivity and can catalyze H 2 S as a source of electrochemical signal generation. The electrochemical sensor constructed based on the above principles has a good electrochemical response to Hcy within the range of 5 μM to 100 μM, and the limit of detection can reach 0.11 μM (S/N = 3). In addition, the constructed sensor has good reproducibility, stability and specificity, and has good recoveries in the detection of real plasma samples, which provides a potential application for the diagnosis of homocysteinemia. Significance and Novelty The electrochemical sensor significantly increases the specificity of detection by utilizing immobilized Hcy specific catalytic enzymes CBS. In addition, Pd modified CuO@COFs electrode greatly increases the conductivity of the electrode, thereby increasing the sensitivity of detection. These characteristics make the electrochemical sensor have good application prospects for detecting the Hcy in clinic in the future.
研究领域:
生物医学工程
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分析化学
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临床诊断
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DOI
高影响因子
JOURNAL OF SOLID STATE CHEMISTRY
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2024
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IF 3.2
Renjie Li,Yaning Xu,Yong Li,Ying Qiao,Dan Tian
Azo dyes, used in large quantities in drinks, have become a threat to human health. In the treatment of dyes, the method of chemical adsorption is often used due to its simple and efficient features. Covalent organic frameworks (COFs) material with the characteristics of stability and porosity has great potential for the adsorption of azo dyes. However, the application of COFs is severely limited by their poor mechanical properties and hard recovery. By the strategy of in situ growth using the original functional groups of the sponge, COFs are successfully grafted onto melamine sponges to give rise to a porous sponge@COFs material. The material can adsorb up to 621 mg g −1 of Congo red, a common azo dye. In addition, it exhibits strong adsorption of iodine solution with the saturated adsorption of 1504.76 mg g −1 . More importantly, sponge@COFs can selectively adsorb azo dyes with S–O - bond. The adsorption mechanism is inferred as the connect of S–O - in the Congo red molecule with O atom of sponge@COFs. Also, the mechanism of iodine adsorption is explained to be due to the coordination of C atoms in COFs with I atom. In addition, as an adsorbent, the material is recoverable, stable and heat resistant. Relying on the stronger performance and lower cost, sponge@COFs is expected to be developed as a new adsorbent.
研究领域:
环境科学
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材料科学
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产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）