Ca2+/Si4+ Modification of the (Gd,Lu)AG Garnet for Enhanced Broadband Cr3+ Luminescence of High Thermal Stability
Near-infrared (NIR)-emitting phosphors with high quantum efficiency and thermal stability are crucial to NIR pc-LEDs. Garnet-structured (GdLuCa)(Al4–zSiCrz)O12 (z = 0.01–0.2) and (Gd2–xLuCax)(Al4.95–xSixCr0.05)O12 (x = 0.2–1.0) new phosphors with promising NIR luminescence under blue light excitation were designed and fabricated by a solid-state reaction in this work. It was analyzed that the Ca2+, Cr3+, and Si4+ ions would replace Gd3+ in [GdO8], Al1 in [Al1O6], and Al2 in [Al2O4], respectively, and the optimal Cr3+ content is z = 0.05, above which concentration quenching would occur via an electric dipole–dipole interaction. Increasing Ca2+/Si4+ substitution up to x = 1.0 led to luminescence enhancement by a factor of up to 1.85 and internal/external quantum efficiency (%) increment from ∼25.9/10.7 to 63.4/27.5, and all of the phosphors showed excellent thermal stability (I423 K/I298 K ≥ 87.6%). The luminescence properties of Cr3+ were discussed in detail through systematic investigation of the effects of Cr3+ and Ca2+/Si4+ contents on the crystal structure, local coordination, and crystal field. With the NIR pc-LED device integrated from the optimal phosphor (x = 1.0) and a blue LED chip, electroluminescence manifested potential applications in night vision and medical diagnosis.
危险品化学品经营许可证（带存储）