Elevating carbonation efficiency and CO2 capture capacity of steel slag by sodium tripolyphosphate (STP): The role of CaCO3 morphology modification
Carbonation degree significantly impacts the volume stability of steel slag powder. To elevate the carbonation efficiency of steel slag and thereby alleviate the volume unsoundness of steel slag powder, sodium tripolyphosphate (STP) was used to enhance the micro morphology of CaCO 3 and accelerate Ca leaching and CO 2 diffusion. Three methods for assessing CO 2 uptake were employed to reliably determine the degree of carbonation. Results indicate that steel slag added with 0.05 wt% STP obtained a promotion exceeded 80 % in CO 2 uptake. Additionally, STP increased the CO 2 capture capacity of steel slag by 24.84 %. Under the influence of STP, the expansion of steel slag paste was reduced by up to 31.45 % following an autoclaving test. The formed micro CaCO 3 particles in carbonated steel slag without STP were polyhedral grains and a dense carbonation layer was formed around calcium silicate. Contrastively, CaCO 3 formed in the carbonated STP incorporated steel slag were conical or acicular particles and consequently generated a porous layer. The porous microstructure provided “tunnels” for the continuous CO 2 diffusion and Ca 2+ leaching and hence maintained relatively higher reaction speed throughout the carbonation process. Furthermore, STP also played the role as a chelator which accelerated the leaching of Ca 2+ .
危险品化学品经营许可证（带存储）