Enhancing mechanical properties of carbonated steel slag through surfactant-assisted CaCO3 crystallization
This study investigates the enhancement of mechanical properties in carbonated steel slag through surfactant-assisted CaCO 3 crystallization. Sodium dodecyl benzene sulfonate (SDBS) was employed at various concentrations (0.1–0.4 mol/L) and temperatures (20–60 °C) to modulate the carbonation process. Optimal performance was achieved with 0.2 mol/L SDBS at 40 °C, resulting in a maximum CO 2 uptake of 8.51 % and a compressive strength of 62.89 MPa, 81.66 % higher than unmodified steel slag. Characterization techniques confirmed the formation of crystalline calcite, vaterite, and aragonite, contributing to improved microstructure and strength. SDBS micelles act as templates for CaCO 3 nucleation and growth, with low concentrations facilitating carbonation and high concentrations inhibiting it. This research offers new insights into surfactant-assisted crystallization for enhancing carbonated steel slag properties, paving the way for high-performance, eco-friendly building materials from industrial waste.
危险品化学品经营许可证（带存储）