Experimental and modeling study of the diffusion path of Ce(III)-EDTA in compacted bentonite
The impact of the diffuse double-layer on the diffusion of radionuclide anions remains unclear, impeding the application of Archie's law for adsorptive anions. Through-diffusion experiments were carried out to measure the effective diffusion coefficient and distribution coefficient of Ce(III) in the presence of EDTA. A multi-porosity model, in combination with Archie's law, was used to estimate the effective diffusion coefficient. The predominant species, CeEDTA − , exhibited an effective diffusion coefficient of (0.88–1.92) × 10 −11 m 2 /s and the distribution coefficient of (0.81–1.18) × 10 −3 m 3 /kg at the compacted dry density of 1300–1800 kg/m 3 . The accessible porosity, the diffuse double-layer porosity, and the interlayer porosity were analyzed using the multi-porosity model, based on the characterization of bentonite via Scanning electron microscopy with energy dispersive spectrometry, X-ray diffractometer , and Nitrogen-Brunner-Emmett-Teller method. Due to the low external surface area of Zhisin bentonite (27.7–35.3 m 2 /g), the impact of the diffuse double-layer was insignificant on the total and accessible porosities. Additionally, the diffuse double-layer porosity had insignificant impact on the effective diffusion coefficient of CeEDTA − in compacted bentonite, as its value was one order magnitude lower than that of the interlayer porosity and the accessible porosity.
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