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Ce/Mn/Cr: Y3Al5O12 phosphor ceramics for white LED and LD lighting with a high color rendering index

Yukun Li,Yongfu Liu,Zhaohua Luo,Zehua Liu,Svenja Hanson,Chengheng Pang,Hui Lin,Haiming Qin,Jun Jiang

Ce/Mn/Cr: Y 3 Al 5 O 12 transparent ceramics with a pure garnet structure and a high color rendering index were prepared by a solid-state reaction method. Mn 2+ and Cr 3+ enhance the emission between 500 and 700 nm and expand the conventional Ce: YAG phosphors spectrum. The Ce 3+ can work both, as activators and sensitizers, and the intense energy transfer from Ce 3+ to Mn 2+ /Cr 3+ is realized through the non-radiative and radiative processes. In the sample with the optimized doping concentration the high color rendering index (CRI) value of 75.3 can be achieved under a 450 nm laser diode excitation. The chromaticity coordinates can be tuned from (0.3125, 0.3232) to (0.2917,0.2851) by varying the doping concentration. With the increasing Mn 2+ /Cr 3+ doping concentration, the lifetime of Ce 3+ , quantum efficiency and luminous efficiency are all gradually decreased. This work effectively offers a scheme for realizing the high color rendering performance of phosphor-converted transparent ceramics in white LEDs/LDs.