Frustrated Lewis pairs created by Ce-doped Bi2MoO6: A universal strategy to promote efficient utilization of H2O2 for Fenton-like photodegradation
Photo-Fenton-like technology based on H 2 O 2 is considered as an ideal strategy to generate reactive oxygen species (ROS) for antibiotic degradation, but O 2 overflow in the process severely limits the utilization efficiency of H 2 O 2 . Herein, we fabricate Bi 2 MoO 6 (BMO) photocatalyst modified with Frustrated Lewis pairs (FLPs) as a Fenton catalyst model for enhancing reuse of spilled O 2 . The FLPs created by the introduction of cerium and oxygen vacancy were found to contribute to regulate the electronic structure of BMO and further improve the acidic and basic properties of photocatalyst surface. More importantly, the frustrated acid and base sites can enhance the H 2 O 2 and O 2 interfacial adsorption process and provide an Ce 4+ -O v -O 2− active site on the surface of Ce-BMO nanosheets, which can promote O 2 /•O 2 − / 1 O 2 /H 2 O 2 redox cycles to achieve high H 2 O 2 utilization efficiency. Specifically, in the experiment using tetracycline as a photocatalytic degradation object, the degradation activity of Ce-BMO was 2.15 times higher than that of BMO pure phase. Quenching experiments and EPR assays also confirmed that 1 O 2 and •O 2 − were the dominant oxidative species. This study systematically reveals the design of Fenton photocatalytic active sites at the atomic scale and provides new insights into constructing FLPs photocatalysts with high H 2 O 2 utilization efficiency.
危险品化学品经营许可证（带存储）