ZIF-8 derived CeO2-Fe3O4@Fe-N/C catalyst for oxygen reduction reaction
Looking for non-noble metal catalysts with low cost, high activity, and high stability to replace platinum in oxygen reduction reaction (ORR) has aroused great concern. According to previous studies, Fe-N x /C material is one of the most promising non-noble metal catalysts for ORR. In this study, new Fe-N x /C material was synthesized by introducing CeO 2 and Fe 3 O 4 nanoparticles into a Fe-N x /C material derived from ZIF-8 as precursors. The new material was called CeO 2 -Fe 3 O 4 @Fe-N/C catalyst and the activity of the catalyst was found to be significantly improved in 0.1 mol L −1 KOH. The half-wave potential of CeO 2 -Fe 3 O 4 @Fe-N/C (0.892 V) is higher than that of Pt/C by 67 mV. In the stability test, the half-wave potential of CeO 2 -Fe 3 O 4 @Fe-N/C was only reduced by 4 mV after 5,000 cycles. The high performance is attributed to the introduction of CeO 2 and Fe 3 O 4 , which gives CeO 2 -Fe 3 O 4 @Fe-N/C enhanced electrocatalytic activity and long-term stability. This approach makes CeO 2 -Fe 3 O 4 @Fe-N/C a promising candidate for cathode catalysts in renewable energy conversion devices.
危险品化学品经营许可证（带存储）