Biological reduction-deposition and luminescent properties of nanostructured CePO4@NaCe(SO4)2(H2O) and CePO4
Nano-sized CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 with hexagonal phase have been prepared by simply varying the reactant P/Ce molar ratio in bacterial liquid. The phase composition of two samples was checked via Fourier transform infrared spectroscopy (FTIR), energy dispersive analysis of X-rays (EDS) and X-ray diffraction (XRD) analyses, displaying the presence of CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 with average crystallite size are 32.34 and 15.61 nm, respectively. The scanning electron microscopy (SEM) images show that nano-clusters and sphere-like in shape with a narrow diameter distribution were observed in two samples. The transmission electron microscopy (TEM) photographs further indicate obtained CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 nanoparticles correspond to nanosheets and nanorods , respectively. The emission spectra of CePO 4 @NaCe(SO 4 ) 2 (H 2 O) and CePO 4 display a broad band of 300–380 nm range with the strongest emission at 342 nm in the violet region.
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