文献检索

查找使用阿拉丁产品的科研文献

检索与阿拉丁产品相关的同行评审论文、DOI、PubMed 编号、期刊、作者、CAS 号及研究领域。

与阿拉丁产品相关的已发表科研成果

在搜索之前,这些指标可帮助访客快速了解产品关联科研的规模与质量。

346,364+ SCI 论文 与阿拉丁产品引用相关

2,295,288.15 总影响因子 匹配文献记录中影响因子的总和

81.20 最高期刊影响因子 匹配期刊中的最高 IF

6.63 平均期刊影响因子 匹配文献的平均 IF

参考指标指标基于阿拉丁文献引用数据库及期刊影响因子记录。文献关联仅供科研参考,请以原始文献为准。

筛选文献

更多筛选

热门产品

Co-Salen

KINETICS AND CATALYSIS · 2018 ·Vol. 58 ·期 6 ·758-762 · IF 0.926

Air Oxidation of Benzoin Catalyzed by Metal-Salen Complexes

Shao Linjun,Chen Qiuling,Qi Chenze

Metal-Salen (M = Fe, Co, Ni, Cu, Zn) complexes were synthesized to catalyze the oxidation of benzoin to benzil with air as the “green” oxidizing reagent. The effects of temperature, base and solvent on M-Salen catalyzed oxidation of benzoin had been examined and optimized. The catalysis results showed that Co-Salen and Fe-Salen complexes were efficient to catalyze the oxidation reaction with yields over 80% while the catalytic activities of other three M-Salen complexes were poor. Moreover, the Co-Salen catalysis system could be reused three times with satisfied yield.

研究领域: 有机化学 · 催化化学

✓ 已验证 DOI 高影响因子

查看原文查看 PubMed

CHEMICAL PAPERS · 2026 · IF 2.7

Metal-center effects of Ce-, Fe-, and Co-Salen complexes in the melt ring-opening polymerization of rac-lactide

Chen Yifei,Sheng Shuqi,Liu Yuqi,Li Qiaoxia,Sun Jiazhe,Zhong Mingqiang,Qu Baiyou,Hu Caixia,Zhao Zhengping

Salen-type Schiff bases, formed by the condensation of salicylaldehyde with diamines, serve as versatile tetradentate N 2 O 2 chelating ligands owing to their tunable electronic and steric structures. Their corresponding metal complexes have been extensively applied as highly efficient and stable catalysts in diverse transformations, particularly in ring-opening polymerization (ROP) reactions. In this study, two structurally related propanediamine-derived bis-Schiff base ligands were synthesized from 3,5-di-tert-butylsalicylaldehyde and corresponding diamines, along with a series of Ce-, Fe-, and Co-Salen complexes. A thorough investigation was conducted on their catalytic performances and influencing factors in the ROP of rac-lactide. The results indicate that the catalytic performance of these Salen-metal complexes is dual-influenced by both the ligand structure and the nature of the metal center. Among the investigated catalysts, the Ce-Salen complex exhibited higher catalytic activity and comparatively favorable M n and dispersity values compared to its Fe- and Co-based counterparts under identical conditions. This comparative study provides valuable insights into the metal-center effects in Salen-type catalysts and offers rational guidance for designing efficient catalysts for PLA synthesis.

✓ 已验证 DOI 高影响因子

查看原文查看 PubMed

已复制

文献关联基于可获得的产品、CAS、DOI 及引用记录。收录不代表作者或出版方对阿拉丁产品的背书,请以原始文献为准。