Synthesis of a Co–Sn Alloy-Deposited PTFE Film for Enhanced Solar-Driven Water Evaporation via a Super-Absorbent Polymer-Based “Water Pump” Design
Solar-driven water evaporation is a promising solution to water pollution, the energy crisis, and water shortages. However, the approach in which the photothermal film is in direct contact with bulk water for water evaporation may lead to a large amount of heat loss, thereby reducing the light-to-heat conversion efficiency (η) of the photothermal film. Here, a highly efficient solar-driven water evaporation system was developed using a Co–Sn alloy-deposited Teflon (PTFE) film (Co–Sn alloy@PTFE) and super-absorbent polymers (SAPs) supported with a floating foam substrate. The Co–Sn alloy with full-spectrum (200–2500 nm) absorption characteristics is devoted to high light-to-heat conversion, while the porous PTFE with high mechanical performance can support the Co–Sn alloy. We used density functional theory to prove that the Co–Sn alloy had a strong adhesive force with PTFE without surfactants due to the high adsorption energy between the (101) crystal plane of the Co–Sn alloy and the hydroxyl group on the PTFE film. Importantly, via the SAP-based “water pump” design, we improved the η of the Co–Sn alloy@PTFE film to 89%, mainly because the SAP not only effectively performed water transportation but also markedly reduced the heat loss of the Co–Sn alloy@PTFE film. Our work highlights the strong potential of Co–Sn alloy@PTFE-based light-to-heat conversion systems for realizing highly effective solar energy-driven water evaporation.
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