A New UV Nonlinear Optical Material CsZn2B3O7: ZnO4 Tetrahedra Double the Efficiency of Second-Harmonic Generation
A new noncentrosymmetric borate CsZn2B3O7 was synthesized by the solid-state reaction techniques. The crystals were obtained by flux method and are of block shape without layering tendency. Single-crystal X-ray diffraction analysis reveals that the crystal structure is composed of [Zn2BO5]∞ two-dimensional layers that are bridged by [B3O6]3– groups to form a three-dimensional framework with one-dimensional channels occupied by Cs+ cations along the a and c axes. Thermal analysis indicates that CsZn2B3O7 melts incongruently. UV–visible–near-IR diffuse reflectance spectrum gives a short absorption edge at 218 nm. CsZn2B3O7 is phase-matchable, with a powder second-harmonic generation (SHG) efficiency of 1.5 × KDP (KDP, potassium dihydrogen phosphate) at 1064 nm, based on the Kurtz–Perry method. These results show that CsZn2B3O7 may have prospects as a UV nonlinear optical material. Interestingly, the SHG efficiency of CsZn2B3O7 is about twice that of γ-KBe2B3O7, a structurally analogous alkaline and alkaline earth borate. First-principles calculations combined with atom-cutting analysis reveal that the ZnO4 tetrhedral groups in CsZn2B3O7 account for the SHG enhancement.
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