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Copper nitrate hydrate as novel high capacity anode material for lithium-ion batteries

Kaiqiang Wu,Dongjie Wang,Lianyi Shao,Miao Shui,Rui Ma,Mengmeng Lao,Nengbing Long,Yuanlong Ren,Jie Shu

For the first time, Cu(NO 3 ) 2 · x H 2 O ( x  ≤ 2.5) is investigated as a new lithium storage anode material for lithium-ion batteries. The impressive characteristic of Cu(NO 3 ) 2 · x H 2 O( x  ≤ 2.5)/Li cell is the high initial discharge capacity reaching to around 2200 mAh g −1 . To make a comparison, Cu(NO 3 ) 2 ·2.5H 2 O electrodes are used as raw materials and heat-treated at 80, 120 and 160 °C. Among all the three samples, Cu(NO 3 ) 2 · x H 2 O ( x  < 2.5) obtained at 160 °C shows the highest reversible capacity of 597.6 mAh g −1 and the best cycling stability after 30 cycles. The difference in electrochemical behaviors is attributed to the variation of surface morphology , crystal water and particles size after heat-treatment at different temperatures. Besides, the thermal reaction results also show that Cu(NO 3 ) 2 · x H 2 O ( x  < 2.5) obtained at 160 °C has the highest thermal stability among all the three samples after repeated cycles. The present findings can provide the fact that Cu(NO 3 ) 2 · x H 2 O (≤2.5) may be a promising anode material for lithium-ion batteries.