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Room temperature synthesis of Cu(Qc)2 and its application for ethane capture from light hydrocarbons

Yuning Tang,Sa Wang,Xin Zhou,Ying Wu,Shikai Xian,Zhong Li

A facile and efficient room-temperature synthesis approach was proposed to prepare MOF material Cu(Qc) 2 (henceforth called RT-Cu(Qc) 2 ) with ultramicropores. RT-Cu(Qc) 2 was successfully synthesized at room-temperature by means of (Zn, Cu) hydroxyl double salt as intermediate within 1–12 h. The resulting RT-Cu(Qc) 2 exhibited excellent water vapor stability and its C 2 H 6 uptake reached 2.19 mmol/g at 288 K and 1 bar. Its C 2 H 6 /C 2 H 4 and C 2 H 6 /CH 4 uptake ratio at 298 K and 1 bar were up to 3.70 and 22.67, superior to benchmark MAF-49, Cu(Qc) 2 and ZIF-7. Its IAST-predicted C 2 H 6 /C 2 H 4 and C 2 H 6 /CH 4 selectivity reached 4.1 (1:1 v:v) and 35.9 (1:9 v:v) at 288 K and 1 bar, higher than most of ethane-capturing MOFs. Molecular simulation revealed well-defined host–guest match between Cu(Qc) 2 and ethane. Fixed bed experiments confirmed that ethane/ethylene or ethane/methane mixtures can be completely separated using RT-Cu(Qc) 2 . RT-Cu(Qc) 2 has great potential for separation of ethane/ethylene and the recovery of ethane from natural gas.