Dual-stimuli-responsive CuS-based micromotors for efficient photo-Fenton degradation of antibiotics
Antibiotics as emerging pollutants in water pose great risks to human health. Due to their persistence in the environment, advanced oxidation processes (AOPs) have been proposed for the degradation of antibiotics. Therefore, developing efficient catalysts for AOPs becomes critical for the removal of antibiotics. Herein, we develop self-propelled CuS-based micromotors (CuS@Fe 3 O 4 /Pt) as active heterogenous catalysts for efficient photo-Fenton degradation of antibiotics. Combining the merits of conventional heterogenous and homogenous catalysts, the prepared micromotors are easy to recycle and free of secondary pollution risks, while demonstrating high degradation efficiency due to self-induced intensification of mass transfer via autonomous motion and microbubble generation. The H 2 O 2 in the Fenton reagents can serve as the fuel for the micromotors to drive their self-propulsion by bubbles generated from catalytic decomposition of H 2 O 2 by the platinum layer. The dual-stimuli-responsiveness of the micromotors to magnetic field and light irradiation allows multi-modes of propulsion and guidance in different systems. The efficient photothermal effect of CuS enables the micromotors to achieve collective phototactic motion toward light, whereas magnetic responsiveness facilitates the recovery and collection of the micromotors. The synergistic effect of CuS and Fe 3 O 4 NPs in H 2 O 2 under visible light irradiation generates a large amount of OH · and · O 2 – to effectively degrade tetracycline within several minutes. With these advantages, the dual-stimuli-responsive CuS-based micromotors provide a new strategy for enhanced degradation of antibiotics in water purification applications.
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