Comparative curing kinetics of 1,4-bis (4-diaminobenzene-1-oxygen) n-butane and 4,4′-bis-(diaminodiphenyl) methane with tetraglycidyl methylene dianiline systems
Aromatic amine curing agent with flexible unit in backbone, 1,4-bis (4-diaminobenzene-1-oxygen) n -butane (DDBE), was synthesized, and the structure was confirmed by FT-IR and 1 H NMR. The curing kinetics of tetraglycidyl methylene dianiline (TGDDM, or AG80) using DDBE and 4,4′-bis-(diaminodiphenyl) methane (DDM) as curing agents, respectively, were comparatively studied by non-isothermal DSC with a model-fitting Málek approach and a model-free advanced isoconversional method of Vyazovkin. The dynamic mechanical properties and thermal stabilities of the cured materials were investigated by DMTA and TG, respectively. The results showed that the activation energy of AG80/DDBE system was slightly higher than that of AG80/DDM system. Šesták-Berggren model can generally simulate well the reaction rates of these two systems. DMTA measurements showed that the storage modulus of cured AG80/DDBE is similar to that of cured AG80/DDM at the temperature below glass transition temperature ( T g ) and lower than that of cured AG80/DDM at the temperature above glass transition temperature, while T g of cured AG80/DDBE is lower than that of cured AG80/DDM. TG showed that the thermal stabilities of these two cured systems are similar.
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