JOURNAL OF CHEMICAL THERMODYNAMICS
·
2017
·
IF 2.726
Dong Fu,Jialin Xie,Fang Wang,Shengqi Wang
The surface tension (γ) and viscosity ( η ) of monoethanolamine (MEA)-methanol (MeOH) and diethanolamine (DEA)-MeOH aqueous solutions were measured by using the BZY-1 surface tension meter and the NDJ-5S digital rotational viscometer. The temperature ranged from 303.2 K to 323.2 K. The mass fractions of MeOH, MEA and DEA ranged from 0.025 to 0.075, 0.2 to 0.4 and 0.2 to 0.4 respectively. Equations were proposed to model the surface tension and viscosity respectively and both the calculated results agreed well with the experiments. The effects of temperature and mass fraction of MeOH/amines on the surface tension and viscosity were demonstrated on the basis of experiments and calculations.
研究领域:
化学工程
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物理化学
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DOI
高影响因子
ChemistrySelect
·
2025
·Vol. 10
·期 37
·e02789
·
IF 2
Li Zhong,Yuxin Duan,Meiying Wang,Xiao Xu,Minghuan Qian,Xu Jia
The polymers of N , N -diethylacrylamide (DEA) exhibit temperature-dependent sensitivity attributable to the presence of both hydrophilic and hydrophobic groups. However, their lower critical solution temperature (LCST) is only 25 °C, a limitation that restricts their practical applications. Previous studies have shown that the incorporation of cationic monomers for copolymerization can enhance the LCST of polymers. In this study, dimethyldiallylammonium chloride (DMDAAC) and DEA were selected for copolymerization to obtain a series of thermosensitive water-soluble polymers, poly(DMDAAC- co -DEA). Structure and properties were characterized using FT-IR, 1 H NMR, TG-DSC, and surface tension test. Combined with the critical phase transition mechanism, it was determined that the hydrophilicity of the polymer underwent a gradual increase in proportion with the increase of DMDAAC blocks in polymers, and the LCST exhibited an increase of up to 36.8 °C. The relationship between polymer structure and demulsification performance was also explored, as represented by the application of O/W emulsion. The experimental findings demonstrated that all poly(DMDAAC- co -DEA) products exhibited effective demulsification performance. The demulsification rate of the polymers with 30%, 50%, and 70% of DMDAAC could reach 97.03%, 98.20%, and 98.40% respectively, which shows great potential for the petroleum demulsification application. Graphical Water-soluble polymer Poly(DMDAAC- co -DEA) are synthesized using a three-step heating method. A comprehensive investigation is conducted into the relationship between its LCST and copolymerization ratio, resulting in the elucidation of the underlying mechanism. Furthermore, the demulsifying properties of the copolymer are investigated.
研究领域:
高分子化学
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石油化学
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胶体与界面科学
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功能材料
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分离技术
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DOI
高影响因子
Separations
·
2024
·Vol. 11
·期 1
·20
·
IF 2.5
Wenxia Xie,Chunmin Tu,Jun Zhang,Chengwei Xu
The accumulation of uncollected fly ash from flue gas in post-combustion CO2capture processes is a significant concern in current coal-fired power plants due to its potential impact on the performance of CO2absorbent and absorption towers. In order to determine the effect of fly ash on the mass transfer performance of CO2absorption into monoethanolamine (MEA) and diethanolamine (DEA) aqueous solutions, experimental studies were carried out using a small-sized packed tower equipped with θ-ring random packing. These studies were conducted under various operating parameters, including solution temperature, liquid/gas ratio (L/G), packing height, and fly ash concentration. The results show that the effect of fly ash on the outlet CO2concentration was primarily observed during the initial stages of the experimental process. Moreover, the presence of fly ash leads to a reduction in the volumetric overall mass transfer coefficient (KGav) when using MEA and DEA solution, and increasing the fly ash concentration further exacerbates this negative impact. However, the effect of fly ash on the reduction inKGavis not significantly related to its chemical composition but rather depends on the operational parameters. With increasing solution temperature, liquid/gas ratio (L/G), and packing height, theKGavvalues for different solutions exhibit an upward trend. The negative effect of fly ash onKGavremains relatively stable for MEA as solution temperature and packing height increase. Compared to MEA, fly ash has a greater negative effect on DEA solution under the same experimental conditions. The analysis reveals that the detrimental effect of fly ash onKGavprimarily stems from its ability to alter the distribution state of the absorption liquid within the packed tower.
研究领域:
环境工程
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化学工程
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DOI
高影响因子
International Journal of Greenhouse Gas Control
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2020
·
IF 3.639
Kang Shunji,Shen Xizhou,Yang Wenze
In this paper, by means of thermo-gravimetric analysis(TGA), the desorption kinetics of CO 2 absorbed in two kinds of rich amine solutions, MDEA (3.25mol/L) and MDEA+DEA(3.25mol/L-0.3mol/L), were investigated under different heating rates(2.5℃/min, 5℃/min, 10℃/min and 20℃/min). The thermal analysis kinetics was applied to analyze the TG-DTG curves of two rich amine solutions so as to research CO 2 desorption kinetics. In addition, the CO 2 desorption kinetics parameters have been calculated with model-free method Flynn-Wall-Ozawa (FWO) and model-fitting method Coats-Redfern (CR). The results indicated that CO 2 desorption process could be divided into two stages. The CO 2 and H 2 O were released with non-uniform speed in the first stage and MDEA or DEA with higher boiling points were evaporated in the second stage. For MDEA solution the average activation energy E was 50.36kJ/mol, the pre-exponential factor A was 1.68×10 7 , and the most probable integral mechanism function was G α = α 3 / 2 . For MDEA+DEA solution the average activation energy E was 59.68kJ/mol, the pre-exponential factor A was 2.22×10 7 , and the most probable integral mechanism function was G α = [ ( 1 + α ) 1 / 3 − 1 ] 2 . The technical feasibility of CO 2 desorption performance in rich amine solutions with thermo-gravimetric analysis method was demonstrated.
研究领域:
化学工程
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环境科学
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DOI
高影响因子
Greenhouse Gases-Science and Technology
·
2021
·Vol. 11
·期 5
·974-987
·
IF 2.013
Shunji Kang,Zhi Shen,Xizhou Shen,Liuya Fang,Li Xiang,Wenze Yang
The carbon dioxide discharged from fossil fuels combustion products is considered as a major contributor to global warming. The current investigation aimed at CO 2 desorption kinetics in 3.25 mol L –1 methyldiethanolamine (MDEA)–0.1 mol L –1 piperazine (PZ) rich amine aqueous solution with thermo-gravimetric analysis (TGA) method under different heating rates of 2.5, 5, 10, and 20 °C min –1 . The kinetics parameters were determined by comparison of 40 mechanism functions with thermal analysis kinetic method. The average activation energy E was 59.16 kJ mol –1 , preexponential factor A was 5.54 × 10 8 , and the most probable mechanism function was G( α ) = [–ln(1 – α )] 3/2 . In addition, the kinetic parameters of CO 2 desorption process from three rich amine aqueous solutions (MDEA, MDEA + diethanolamine(DEA), MDEA + PZ) were compared and the influence of kinetic parameters was further discussed. The desorption rate models of three rich amine aqueous solutions were established and desorption rates were well predicted. The order of desorption rate inferred from desorption rate model was MDEA > MDEA + DEA > MDEA + PZ. The results indicated that TGA combined with thermal analysis kinetics was an effective and quick method with high accuracy, easy operation, and good repeatability for screening absorbents preliminarily in laboratory. © 2021 Society of Chemical Industry and John Wiley & Sons, Ltd.
研究领域:
化学工程
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环境科学
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热分析
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DOI
高影响因子
Molecular Catalysis
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2023
·
IF 4.6
Zhenhua Zhai,Xiaoyan Shan,Mingming Li,Ying Liu,Feng Yang,Fuke Wang,Zhiqiang Tian,Keren Shi,Huiqin Yao
In this work, poly(N',N-diethylacrylamide-co-4-vinylphenylboronic acid) (P(DEA-co-VPBA)) hydrogel films were successfully assembled on the pyrolytic graphite (PG) electrode by a simple radical polymerization. Reversible thermal, glucose and pH-triggered electrochemical reactions were obtained in the presence of 1,1′-ferrocene dicarboxylic acid (FDA) with electro-redox properties. The thermal response performances of the thin-film electrode were attributed to the PDEA component, the sensitive behaviors of glucose were ascribed to the VPBA component, and the sensitive behaviors of pH were affected by PDEA and VPBA. The electrocatalytic oxidation of l -cysteine by FDA on the hydrogel film electrodes significantly enhanced the difference between the on and off states of the multi-response cyclic voltammetry (CV) signals. This smart polymer hydrogel film electrode with amplified signals could be further used to realize a 4-input/9-output binary logic circuit, which was constructed with temperature, glucose, pH, and cysteine as inputs and different levels of I pa and I pc responses as outputs. Furthermore, a 2-to-4 decoder, a 4-to-2 encoder, and a 4-input keypad lock were built on the same platform. This polymer electrocatalysis system provides a novel idea for constructing complex biological computing systems.
研究领域:
材料科学
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电化学
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生物医学工程
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纳米技术
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计算生物学
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DOI
高影响因子
Chemical Engineering and Processing-Process Intensification
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2024
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IF 3.8
Lingyu Xiao,Zhoujie Qiu,Shuo Feng,Xiaoxu Duan,Zhisheng Zhao,Yongcong Liu,Liang Ma
The global climate change problem has brought much attention to CO 2 capture technology. N-methyldiethanolamine (MDEA), as an efficient and environmentally friendly absorbent, is widely used in CO 2 capture. However, it is difficult for a single MDEA to meet the demand for efficient absorption and desorption under certain conditions, so the addition of promoters to improve its performance has become a hot research topic. The aim of this study is to deeply investigate the effects of different accelerators on the absorption and desorption of CO 2 by MDEA. Experiments were conducted to measure the absorption capacity of the MDEA compound solution for CO 2 in a bubbling reactor at 30°C and to evaluate its desorption effect in a desorption system at 90°C. The experimental results showed that increasing the promoter concentration in the MDEA-based absorbent solution significantly enhanced the absorption capacity and circulation capacity. However, in terms of desorption efficiency, the added concentrations of MEA and DEA were negatively correlated with the desorption efficiency. Notably, the addition of 0.1 mol/L DEA significantly enhanced the desorption efficiency by 16% compared with MDEA.
研究领域:
环境科学
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化学工程
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DOI
高影响因子
MICROPOROUS AND MESOPOROUS MATERIALS
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2012
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IF 3.285
Martin Kubli,Dubravka Šišak,Christian Baerlocher,Lynne B. McCusker,Lei Liu,Jiangfeng Yang,Jinping Li,Jinxiang Dong
A microporous zirconium phosphate material with the chemical composition |(C 4 H 12 N + ) 6 (H 3 O + ) 2 (H 2 O) 2 |[Zr 32 P 48 O 176 F 8 (OH) 16 ] (ZrPOF-DEA) has been synthesized ionothermally using diethylammonium chloride and oxalic acid to form the deep eutectic solvent. It is closely related to the analagous ethylammonium material ZrPOF-EA, which has already been shown to discriminate very well between CO 2 and CH 4 . The framework structures, with two different 8-ring channels running parallel to the x -axis, one of which intersects a 7-ring channel running parallel to the z -axis, proved to be identical. Only the positions of the non-framework cations and water molecules differ. The structure of ZrPOF-DEA ( Pbam , a = 20.03757(1) Å, b = 37.19099(1) Å, c = 6.62488(1) Å) was solved from synchrotron powder diffraction data using the charge-flipping algorithm in Superflip . Difference Fourier analyses were then used to locate the non-framework species in the channels. Rietveld refinement of the final structure converged with R F = 0.037 and R wp = 0.138. Although this material, like ZrPOF-EA, is stable up to 410 °C, it does not discriminate as well between CO 2 and CH 4 . Thermogravimetric analysis shows that not all of the organic species have been removed at 410 °C, and this is presumably the reason for the poorer adsorption results.
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DOI
高影响因子
CHEMICAL ENGINEERING JOURNAL
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2024
·
IF 13.3
Zhipeng Chen,Tao Wang,Chao Li,Mengxiang Fang,Wei Chen,Ximing Hu,Yan Shao,Zhihao Liu,Wei Zhang,Li Zhang,Wenyang Fan,Shaojuan Zeng
Lower regeneration energy and superior cyclic capacity have enabled biphasic absorbents great potential in the area of flue gas CO 2 capture. The liquid film mass transfer coefficient(k L ) is a vital parameter in the development of absorbents with efficient CO 2 absorption mass transfer performance, while the phase separation behavior of biphasic solutions could be an essential factor for the absorption mass transfer and the stability of absorber. However, systemic kinetic research towards biphasic absorbents, especially the impact of phase separation behavior, is limited. In this study, a typical amide-based biphasic absorbent diethylenetriamine(DETA)/diethanolamine(DEA)/N, N-dimethylacetamide(DMAC) which has achieved great reduction in regeneration energy, was selected as the subject of kinetic investigation in a wetted wall column. The CO 2 overall mass transfer coefficient(K G ) of DETA/DEA/DMAC exceeded other biphasic solvents, blended amine solution, and 40% K 2 CO 3 solution, with 3 times that of 40% K 2 CO 3 solution. Moreover, various operational conditions including absorption temperature, gas flow rate, and water content of solution were taken into account to build a multiple-condition kinetic mechanism to offer guidance for biphasic absorbents. Furthermore, phase separation behavior was revealed as the main blame for the deterioration in the liquid film chemical mass transfer process of biphasic solvents in the CO 2 absorption process, resulting in the k L of DETA/DEA/DMAC before phase separation decreased by 75.3% at the phase separation stage. Therefore, it is crucial to ensure that the CO 2 loading of the solution entering absorber is lower than the phase separation point in applications. After phase separation, DETA/DEA/DMAC split into the organic and aqueous phases, the k L of the aqueous phase gradually exceeded that of the organic phase as CO 2 loading increased for its higher chemical enhancement factor(E).
研究领域:
化学工程
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环境科学
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产品关联
DOI
高影响因子
AICHE JOURNAL
·
2018
·Vol. 64
·期 7
·2515-2525
·
IF 3.326
Helei Liu,Moxia Li,Xiao Luo,Zhiwu Liang,Raphael Idem,Paitoon Tontiwachwuthikul
In this work, Diethanolamine (DEA) was considered as an activator to enhance the CO 2 capture performance of Monoethanolamine (MEA). The addition of DEA into MEA system was expected to improve disadvantages of MEA on regeneration heat, degradation, and corrosivity. To understand the reaction mechanism of blended MEA-DEA solvent and CO 2 , 13 C nuclear magnetic resonance (NMR) technique was used to study the ions (MEACOO - , DEACOO – , MEA, DEA, MEAH + , DEAH + , , ) speciation in the blended MEA-DEA-CO 2 -H 2 O systems with CO 2 loading range from 0 to 0.7 mol CO 2 /mol amine at the temperature of 301 K. The different ratios of MEA and DEA (MEA: DEA = 2.0:0, 1.5:0.5, 1.0:1.0, and 0:2.0) were studied to comprehensively investigate the role of DEA in the system of MEA-DEA-CO 2 -H 2 O. The results revealed that DEA performs the coordinative role at the low CO 2 loading and the competitive role at high CO 2 loading. Additionally, the mechanism was also proposed to interpret the reaction process of the blended solvent with CO 2 . © 2018 American Institute of Chemical Engineers AIChE J , 64: 2515–2525, 2018
研究领域:
化学工程
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环境科学
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DOI
高影响因子
IEEE-ASME TRANSACTIONS ON MECHATRONICS
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2021
·Vol. 26
·期 6
·3151-3162
·
IF 5.303
Chongjing Cao,Lijin Chen,Wenke Duan,Thomas L. Hill,Bo Li,Guimin Chen,Hui Li,Yingtian Li,Lei Wang,Xing Gao
The emerging demand for bioinspired soft robotics requires novel soft actuators whose performance exceeds conventional rigid ones. Dielectric elastomer actuators (DEAs) are a promising soft actuation technology with large actuation strain and fast response. Cone DEAs are one of the most widely adopted DEA configurations for their compact structure and large force/stroke output with several configuration variations developed in recent years. By driving at a resonant frequency, the cone DEAs show a significant amplification in their power outputs, which demonstrates their suitability for highly dynamic robotic applications. However, it is still unclear how the payload conditions could affect the power outputs of cone DEAs and no work has compared the output performance of different variations of cone configurations. In this article, by considering conical configuration DEAs with generalized dissipative payloads, we conduct an extensive study on the effects of payload conditions on the power outputs of the cone DEA family. Additionally, we benchmark the performance of different cone DEA configurations and illustrate the fundamental principles behind these output patterns. The findings reported in this article establish guidelines for designing high-performance cone DEA actuators.
研究领域:
软体机器人
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智能材料
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致动器技术
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机械工程
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DOI
高影响因子
DALTON TRANSACTIONS
·
2020
·Vol. 49
·期 18
·6119-6126
·
IF 4.174
Jinyuan Zhang,Huaimin Gu
Owing to their environmentally friendly characteristic, InP-based quantum dots (QDs) show great potential in various fields as an alternative to Cd-based QDs. However, the current mainstream synthesis process, the (TMS)3P-based injection method, still faces many challenges, such as the high cost of (TMS)3P and complex temperature control. In contrast, the solvothermal method is considered to be more feasible and reproducible. Despite its potential advantages, little has been done to understand how the precursors influence the synthesis of InP QDs using the solvothermal method. In this research, InZnP/ZnS QDs were synthesized using practical phosphorus precursors (DEA)3P or (DMA)3P. Through the feasible regulation of zinc, indium, phosphorus and sulfur precursors, the band gap of the QDs could be widely and accurately tuned, and a much wider photoluminescence wavelength ranging from 484 nm to 651 nm could be achieved. Furthermore, InI3 and InBr3 contributed to the blueshift in the PL wavelengths, and the combination of (DEA)3P, (DMA)3P, n-DDT and t-DDT refined the PL wavelength with a small tuning gap of 5 nm.
研究领域:
材料科学
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纳米技术
·
化学
✓ 已验证
产品关联
DOI
PubMed
高影响因子
危险品化学品经营许可证（带存储）