The role of magnetic MOFs nanoparticles in enhanced iron coagulation of aquatic dissolved organic matter
Dissolved organic matter (DOM) is not only a vector for the migration of aquatic environmental pollutants, but is also key to the control of water pollution . Economic and effective DOM removal through coagulation is essential in water treatment processes. This work investigated the role of carboxylated magnetic metal organic frameworks (MMOFs) nanoparticles in polymeric iron-based coagulation for the removal of aquatic DOM using a MMOFs-doped polyferric iron-based coagulant (MMOF-PIC). Analytical methodologies and tools used in this research included scanning electron microscopy (SEM), zeta potential , molecular weight cut off (MWCO), vibrating sample magnetometer (VSM) measurement, excitation emission matrix spectroscopy (EEMs), and X-ray photoelectron spectroscopy (XPS). The results showed that MMOF-PIC had the potential to change the structure of the polyferric iron-based coagulant (PIC) and charge, as determined by a porous surface morphology, a higher medium polymeric species distribution, and a more positive zeta potential. The MMOFs consequently enhanced PIC action on the removal of UV254 exposed DOM species with molecular weight <30 kDa, including aromatic C C based compounds, org-N as primary amines and amide/peptide bound species, water containing microbial metabolites and protein-like materials. The coagulation of DOM was enhanced by improving charge neutralization, adsorption-bridging and sweep-flocculation in the presence of MMOFs nanoparticles. This was due to hydrogen bonds , π-π bonds and covalent bonds resulting from actions of nanoparticles and pollutants. These results indicate that magnetic MOF nanoparticles can improve PIC coagulation for DOM, enhancing future removal of target pollutants.
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