Sorption of Uranium on a Bifunctional Polymer of Diethylenetriaminepentaacetic Acid Cross-Linked β-Cyclodextrin in the Presence of Humic Acid: Kinetics, Isotherms, and Thermodynamics
Humic acid (HA) plays an important role in the migration and transformation of uranium in natural waters. To effectively remove uranium in the presence of HA, a bifunctional polymer, diethylenetriaminepentaacetic acid cross-linked β -cyclodextrin (DTPA- β -CD), was synthesized by polycondensation reaction. The sorption performance of DTPA- β -CD in functions of pH, ionic strength, contact time, initial time, and temperature were explored batch wise. Experimental results showed that DTPA- β -CD could concurrently sorb uranium and HA around pH of 3.0. The sorption strongly depended on pH and on ionic strength, demonstrating outer-sphere surface complex in nature. Two sorption kinetics well followed pseudo-second-order model. Sorption isotherm accorded with Sips model. Increasing temperature facilitated uranium and restrained HA sorption. This work demonstrated that DTPA- β -CD was a promising material for sorbing uranium in the presence of HA.
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