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EPDM弹性体
JOURNAL OF APPLIED POLYMER SCIENCE · 2020 ·Vol. 138 ·期 5 ·49767 · IF 2.52

A thermally reversible healing EPDM based elastomer with higher tensile properties and damping properties

Chengtian Xiong,Xiaoqing Li,Hezhi He,Bin Xue,Yi Wang,Jiqian Li,Zhiwen Zhu

Due to the disadvantages of lower tensile strength and fracture toughness, the widely application of Ethylene-propylene-diene-monomer rubber (EPDM) has been limited. In this study, a thermally reversible healing EPDM based elastomer with H-bonding and Zn-based-bonding dynamic cross-link network was prepared. The influence of mole ratio of ATA/MAH on tensile strength and fracture energy of mEPDM 0 -xATA was investigated. The results showed that increasing the content of ATA brings about a gradual improvement in tensile strength of the mEPDM 0 -xATA. Especially when the mole ratio of ATA/MAH is 1, the fracture energy of mEPDM 0 -ATA is dramatically enhanced to 33.9 MJ/m 3 , which is best among the ratios studied in our research. After curing, the effect of ZnCl 2 content on tensile strength and fracture energy of mEPDM-ATA-nZn was also studied. Meanwhile, the uniaxial cyclic loading-unloading tensile test was used to study the viscous damping properties of mEPDM-ATA-0.4Zn, which showed reversible repair properties after heat treatment. The results of dynamic rheological measurement showed that the damping properties were improved.

研究领域: 材料科学 · 高分子化学
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