Reduced Amino Acid Schiff Base-Iron(III) Complexes Catalyzing Oxidation of Cyclohexane with Hydrogen Peroxide
Graphical Reduced amino acid Schiff base-iron(III) complexes have been developed and employed as catalysts for the selective oxidation of cycloalkanes and aromatics into alcohols/ketones and phenols with H 2 O 2 as an oxidant, respectively. The iron complexes catalyze the oxidation reaction via a heterogeneous manner and are capable to be recyclable. The reduced amino acid Schiff base ligands have been prepared and were coordinated with ferric chloride to generate the iron(III) complexes. The ligands and complexes have been characterized using FT-IR, UV-vis, elemental analysis, ICP-AES analysis, mass spectra etc. After the structural characterization, these complexes were applied for the oxidation of cyclohexane using hydrogen peroxide as the oxidant under mild conditions. The activity tests showed that the L-phenylalanine-derived reduced Schiff base iron(III) complex(Ph−FeCl) afforded the highest yield of cyclohexanol and cyclohexanone(total yield up to 23.2 %). Notably, the Ph−FeCl complex catalyzes the reaction via a heterogeneous approach, allowing the complex to be separated and recycled conveniently after the oxidation reaction. Besides, the Ph−FeCl catalyst can also be extended for the selective oxidation of other alkanes and aromatics into alcohols, ketones and phenols etc. Finally, the reaction mechanism of cyclohexane oxidation on the iron(III) complex was proposed as well by the free radical inhibitors and EPR study of active intermediates.
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