MATERIALS RESEARCH BULLETIN
·
2013
·
IF 1.913
Jintai Lin,Zhan Zhou,Qianming Wang
GdNbO 4 :Eu 3+ and LuTaO 4 :Eu 3+ have been successfully prepared with different fluxes (NaCl, KCl, NaCl and KCl) by the molten salt method. X-ray diffraction (XRD) patterns illustrated that well crystallized GdNbO 4 :Eu 3+ and LuTaO 4 :Eu 3+ in the presence of fluxes were formed under reduced temperature (900 °C) in contrast to conventional method (GdNbO 4 :Eu 3+ : around 1200 °C; LuTaO 4 :Eu 3+ : around 1500 °C). Scanning electron microscope (SEM) images revealed that well dispersed particles were achieved (granular or rod-like structures). Meanwhile, the photo-luminescent studies demonstrated that both niobate and tantalate are efficient hosts to sensitize europium red emissions. The results indicated that GdNbO 4 :Eu 3+ using NaCl as the flux gave much enhanced red emission whereas LuTaO 4 :Eu 3+ synthesized with the assistance of mixed salts (NaCl–KCl) achieved the best luminescence.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE
·
2022
·Vol. 57
·期 43
·20210-20223
·
IF 4.682
Wang Ruo-tian,Xiong Sang
Nano-WO 3 :EU 3+ powder was prepared by Pechini method under acidic and alkaline condition, and the prepared acidic nano-WO 3 :Eu 3+ mixed with the silver nanowires (AgNWs) in ethanol and acetone solution. The solution was mixed with PMMA and EP, respectively. Then, drops of the solutions were added to the indium tin oxide (ITO) conductive glass as the substrate; a AgNWs/WO 3 :Eu 3+ composite film was obtained with spin coating by spin coater and solidification process. Microstructure, morphology, optical properties, preparation process and UV transmittance of the prepared nano-WO 3 :Eu 3+ and AgNWs/WO 3 :Eu 3+ composite films were investigated by XRD, SEM, fluorescence spectroscopy and UV spectrophotometer. The results show that the prepared acidic nano-WO 3 is triclinic, and the average particle size is 71.63 nm. The prepared alkaline nano-WO 3 is monoclinic, with an average particle size of 95.66 nm. Both of them have good luminescence properties. Under different monitoring wavelengths, in the emission range of 450–500 nm, it belongs to the green light region, and its excitation peak is the largest, indicating that green light is the best excitation light source for WO 3 :Eu 3+ powder. The transmittance of EP/AgNWs/WO 3 :Eu 3+ composite film is the highest when the spin coating time is more than 30 s and above 3000 rpm, no more than three layers spin coating and the content of curing agent is between 0.1 and 0.2 g.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
ECS Journal of Solid State Science and Technology
·
2022
·Vol. 11
·期 6
·066004
·
IF 2.483
Yu-Guo Yang,Qing-Li Luo,Lei Wei,Hua-Jian Yu,Cheng-Cheng Qiu,Qing-Gang Li,Xu-Ping Wang,Bing Liu,Ji-Yang Wang,Jing-Feng Li
The Dy3+/Eu3+ doped CaBi2Ta2O9 phosphors had been obtained via the sintering processes at 1200 °C for 3 h. The phase and luminescence performance of the prepared phosphors had been researched. The X-ray diffraction results indicate the pure orthorhombic phase of the prepared phosphors. When the phosphors are excited at 355 nm, the Dy3+/Eu3+ single doped CaBi2Ta2O9 phosphors exhibit the characteristic emission bands corresponding to Dy3+ and Eu3+, and the Dy3+/Eu3+ codoped CaBi2Ta2O9 phosphors exhibit tunable luminescence on account of the Dy3+ → Eu3+ energy transfers. In this process, the dipole-dipole interaction is dominated.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS
·
2016
·Vol. 27
·期 6
·6188-6192
·
IF 1.798
Wu Yeqiu,Jin Guangya,Liu Zhijian,He Tao
Y 2 O 3 :Eu 3+ and Y 2 O 3 :Eu 3+ /Bi 3+ particles with spherical morphology are synthesized by microwave-assistant hydrothermal process. The results show that cubic phase Y 2 O 3 :Eu 3+ and Y 2 O 3 :Eu 3+ /Bi 3+ particles with uniform size and spherical shape are obtained. The doping Eu 3+ and Bi 3+ ion have no influence on the phase and morphology of samples. In the hydrothermal process, the fast and homogeneous microwave heating benefits the formation of samples with uniform size and spherical shape. Both Y 2 O 3 :Eu 3+ and Y 2 O 3 :Eu 3+ /Bi 3+ show dominant red emission originating from the 5 D 0 → 7 F 2 transition of Eu 3+ . The codoping Bi 3+ can enhance the intensity of Eu 3+ emission.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2020
·Vol. 10
·期 16
·9444-9449
·
IF 3.119
Leipeng Li,Yuan Zhou,Feng Qin,Jipeng Miao,Yangdong Zheng,Zhiguo Zhang
Recently, luminescence ratiometric thermometry has gained ever-increasing attention due to its merits of rapid response, non-invasiveness, high spatial resolution, and so forth. For research fields relying on temperature measurements, achieving a higher relative sensitivity of this measurement is still an important task. In this work, we developed a strategy for achieving a more sensitive temperature measurement, one merely depending on the photoluminescence of Eu3+. We showed that using the 5D1–7F1 transition and the hypersensitive 5D0–7F2 transition of Eu3+ can boost the relative sensitivity compared with the method relying on the 5D1–7F1 and 5D0–7F1 transitions of Eu3+. The difference between these two strategies was studied and was explained by the hypersensitive 5D0–7F2 transition more steeply decreasing than the 5D0–7F1 transition with a rise in temperature. Our work is expected to help researchers design sensitive optical thermometers via proper use of this hypersensitive transition.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
JOURNAL OF LUMINESCENCE
·
2022
·
IF 4.171
Erlei Wang,Kun Feng,Jia Li,Xiaodong Zhou,Xianke Sun
A series of Bi 3+ /Tb 3+ /Eu 3+ doped NaYGeO 4 phosphors were synthesized via the solid state sintering at 1300 °C for 3 h. The phase and luminescence performance of the synthesized phosphors were investigated. The Bi 3+ , Tb 3+ and Eu 3+ single doped NaYGeO 4 phosphors show the prominent blue, green and red emission, respectively. And the emission shows obvious dependence on doping concentration and excitation wavelength. The Bi 3+ → Tb 3+ /Eu 3+ energy transfers were confirmed by the luminescence characteristics of the Bi 3+ /Tb 3+ , Bi 3+ /Eu 3+ and Bi 3+ /Tb 3+ /Eu 3+ doped NaYGeO 4 phosphors. The Bi 3+ → Tb 3+ energy transfer in the NaYGeO 4 :Bi 3+ /Tb 3+ phosphors leads to the tunable emission from the blue to cyan-green light region and the Bi 3+ → Eu 3+ energy transfer in the NaYGeO 4 :Bi 3+ /Eu 3+ phosphors leads to the tunable emission from the blue to purple-red light region. But in the NaYGeO 4 :Bi 3+ /Tb 3+ /Eu 3+ phosphors, the Bi 3+ → Tb 3+ /Eu 3+ energy transfers lead to the tunable emission from the blue to yellow light region through the white light region. From the luminescence characteristics of the Bi 3+ /Tb 3+ /Eu 3+ doped NaYGeO 4 phosphors, the energy transfer mechanisms were speculated.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
MATERIALS RESEARCH BULLETIN
·
2022
·
IF 5.6
Renping Cao,Zhiyi Huang,Bang Lan,Lan Li,Xuehua Yi,Zhiyang Luo,Chenxing Liao,Jing Wang
Ca 3 Zn 3 Te 2 O 12 :Bi 3+ , Ca 3 Zn 3 Te 2 O 12 :Eu 3+ , Ca 3 Zn 3 Te 2 O 12 :Eu 3+ /Bi 3+ are prepared successfully in air. The crystal phase, microscopic image, and optical properties of samples are investigated by the X-ray difractometer, scanning electron microscopy, and edinburgh steady-state FLS 980 spectrograph. The green emission of Ca 3 Zn 3 Te 2 O 12 :Bi 3+ phosphor with excitation at 314 nm is observed and its broad emission spectrum in the range of 360 - 790 nm is attributed to the 3 P 1 → 1 S 0 transition of Bi 3+ ion. Under excitation at 395 nm, the red emission of Ca 3 Zn 3 Te 2 O 12 :Eu 3+ is found, the chromaticity coordinates are (0.6392, 0.3605), and its PL spectrum is in the rang of 575 - 750 nm because of the 5 D 0 → 7 F 0 , 7 F 1 , 7 F 2 , 7 F 3 , and 7 F 4 transations of Eu 3+ ion. The doping Bi 3+ ion can affect the luminescence properties of Ca 3 Zn 3 Te 2 O 12 :Eu 3+ phosphor. The adjustable color light from green to yellow of Ca 3 Zn 3 Te 2 O 12 :Eu 3+ , Bi 3+ phosphor with excitation at 314 nm is revealed when Eu 3+ concentration is changed from 0 to 12 mol%. When the excitation wavelength is 395 nm, Ca 3 Zn 3 Te 2 O 12 :Eu 3+ , Bi 3+ phosphor only emits red light with emission spectrum in the rang of 575 - 750 nm. The energy level diagrams of Eu 3+ and Bi 3+ in Ca 3 Zn 3 Te 2 O 12 :Eu 3+ , Bi 3+ are drawn, which is used to analyze the luminous mechanism of samples.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
RSC Advances
·
2018
·Vol. 8
·期 56
·32325-32332
·
IF 2.936
Yuhan Zhu,Yu Pan,Wenjun Wang,Haibing Xu,Liqun Zhou,Xiaoguang Liu,Ling Li
The local crystal sites occupied by Eu3+ in Ca5(BO3)3F:1% Eu3+ phosphor were investigated experimentally and theoretically. Ca5(BO3)3F:1% Eu3+ was synthesized by high-temperature solid-state method in air. The crystal structure and optical properties of the phosphor were studied by X-ray powder diffraction and photoluminescence, respectively. Two different O2− → Eu3+ CT broad bands with the peaks at 266 and 283 nm in Ca5(BO3)3F:1% Eu3+ were detected, indicating the Eu3+ sites occupied Ca2 and Ca1, respectively. The different sharp f–f emission spectra under the excitation of 283 and 266 nm proved that there are two different local lattice environments around Eu3+ existing in Ca5(BO3)3F:1% Eu3+. Environmental factor he, the standard deviation of environmental factor (EFSD) and the bond energy were used to illustrate and explain the site occupancy mechanism of Eu3+ into the host lattice. By comparing the intensity ratios of 5D0 → 7F2 transition to the 5D0 → 7F1 transition, I(5D0/7F2)/I(5D0/7F1) of Eu3+ at Ca2 (7.381) was found to be 2.5 times stronger than that of Eu3+ at Ca1 site (2.933). was calculated to analyze the I(5D0/7F2)/I(5D0/7F1) value. On the basis of the bond valence model, a bond-energy method was used to study the occupancy of the Eu ion, which indicated that the preferential sites of Eu ion occupancy in the Ca5(BO3)3F are the Ca2 and Ca1 sites. All three theoretical calculation results are consistent with each other.
研究领域:
材料科学
·
固体化学
·
光学
·
晶体学
✓ 已验证
DOI
高影响因子
Optical Materials Express
·
2016
·Vol. 6
·期 2
·374-380
·
IF 2.657
X. Y. Chen,Z. J. Zhang,F. F. Xu,S. Q. Shi,J. T. Zhao
A color-tunable fluorescence composite bulk based on carbon dots and Y2WO6: Eu3+ as blue and red emitting materials, respectively, was fabricated. Due to the different excitation regions of the two materials, the emission color of the composite can be tuned from red, across magenta into the blue via varying excitation wavelengths. At the same time, the material is still considerably optically transparent, which demonstrates a clear advantage for integration into real applications.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
Journal of Applied Spectroscopy
·
2020
·Vol. 87
·期 4
·753-757
·
IF 0.71
Sun J.,Li Q.,Zhou Q.
Eu 3+ -doped NaLaMo 2 O 8 phosphors were synthesized by a conventional solid-state reaction. The phase and luminescent properties of the synthesized phosphors were investigated in the current work. In NaLaMo 2 O 8 , Eu 3+ ions replace La 3+ ions and form solid compound. This substitution induces the 2θ angles of diffraction peaks to shift to larger values. Under excitation at 395 nm, NaLaMo 2 O 8 :Eu 3+ phosphors exhibit emission bands in the range of 550–725 nm originating from 5 D 0 → 7 F J transitions (J = 0, 1, 2, 3, 4) of Eu 3+ . The strongest emission band corresponds to the 5 D 0 → 7 F 2 transition, which indicates a site of Eu 3+ without inversion symmetry in NaLaMo 2 O 8 . The Eu 3+ concentration has obvious influence on the luminescent properties of NaLaMo 2 O 8 :Eu 3+ phosphors. NaLaMo 2 O 8 :6 mol%Eu 3+ has the strongest excitation and emission intensities.
研究领域:
材料科学
·
光学
✓ 已验证
DOI
高影响因子
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
·
2018
·Vol. 102
·期 4
·1822-1831
·
IF 2.956
WeiHui Song,XueYan Chen,LiMing Teng,ZhiGang Zheng,Jun Wen,FangFang Hu,RongFei Wei,LiPing Chen,Hai Guo
Single-composition Ba 2 Y 2 Si 4 O 13 :Bi 3+ ,Eu 3+ (BYSO:Bi 3+ ,Eu 3+ ) phosphors with color-tunable and white emission were prepared by conventional high temperature solid-state reaction method. The structural and luminescent properties of these phosphors were thoroughly investigated through X-ray diffraction, photoluminescence, and decay curves. BYSO:Bi 3+ phosphors show two excitation peaks at 342 and 373 nm, and give two emission peaks at 414 and 503 nm, respectively, indicating that there are two sites of Bi 3+ in BYSO. The energy transfer from Bi 3+ to Eu 3+ was investigated in detail. Varied hues from blue (chromaticity coordinate [0.219, 0.350]) to white (0.288, 0.350) and orange-red light (0.644, 0.341) can be generated by adjusting the content of Eu 3+ . Pure white light emission (0.311, 0.338) can be obtained under the excitation of 355 nm in BYSO:3%Bi 3+ ,20%Eu 3+ phosphor. Besides, BYSO:Bi 3+ ,Eu 3+ phosphors exhibit distinct thermal quenching properties, whose emission intensity at 473 K is 82.6% of that at 298 K. Our results indicate that BYSO:Bi 3+ ,Eu 3+ may be applied as conversion phosphors for n-UV-based W-LEDs.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
OPTIK
·
2019
·
IF 1.914
Yulin Shi,Yudong Xu,Wenjie Hu,Lei Wang,Ruliang Liu,Heni Wang,Caiyue Zhao,Xinyi Chen,Min Shi
In this article, the authors prepared CaMgAl 10 O 17 : Sm 3+ , CaMgAl 10 O 17 : Eu 3+ and CaMgAl 10 O 17 : Sm 3+ , Eu 3+ phosphors via high temperature solid-state reaction and studied the phase constituents and photoluminescence (PL) of the phosphors as-synthesized. The main emission peaks of CaMgAl 10 O 17 : Sm 3+ at 559 nm, 590 nm and 639 nm are due to 4 G 5/3 → 6 H 5/2 , 4 G 5/3 → 6 H 7/2 and 4 G 5/3 → 6 H 9/2 transitions of Sm 3+ activator, respectively. The optimum doping concentration of Sm 3+ in CaMgAl 10 O 17 is 3 mol. %. The main emissions of CaMgAl 10 O 17 : Eu 3+ peaked at 586 nm and 610 nm belong to 5 D 0 → 7 F J (J = 1, 2) transitions of Eu 3+ activator. When Eu 3+ ions are added into CaMgAl 10 O 17 : 0.03 Sm 3+ phosphors, an energy transfer between Sm 3+ and Eu 3+ via an electrical multipole interaction occurs, and the emission intensity of CaMgAl 10 O 17 : 0.03 Sm 3+ , Eu 3+ phosphors is greatly improved.
研究领域:
材料科学
·
光学
✓ 已验证
产品关联
DOI
高影响因子
危险品化学品经营许可证（带存储）