Xiaoyang Yu,Fan Li,Xuyang Miao,Ning Jiang,Ruowen Zong,Shouxiang Lu,Changhai Li
The presence of ethanol has an adverse effect on foam spreading, and ethanol fire is difficult to extinguish with aqueous fire-fighting foams. Thus, it is necessary to explore the foam formulation suitable for ethanol fuels and study the spreading behavior of foam over ethanol surface. In the current work, stable foams based on hydrocarbon surfactant (SDS), fluorocarbon surfactant (FC1157), and polymers (XG) were prepared by using the compressed-air foam system. The spreading behaviors of foam on polar ethanol and non-polar heptane surface were observed and compared. Furthermore, the effects of stabilizer concentrations, foam flow rates and expansion ratios on foam spreading performance were investigated, respectively. The results indicate that aqueous SDS foam can spread on the heptane layer continuously, but it is difficult to cover the ethanol surface. The addition of XG and FC1157 can synergistically improve the spreading performance of aqueous foam over ethanol. Depending on stabilizer concentrations, there are remarkable differences in foam spreading behaviors. Besides, different foam application parameters including expansion ratios and foam flow rates significantly affect the foam spreading rate, despite the same foam formulation. The research methods and results guide the optimal design of foam formulations as well as the practical application of aqueous foam for ethanol fire extinguishment.
Qian Li,Xiaoyang Yu,Jin Lin,Ke Qiu,Huan Li,Shouxiang Lu
The effect of carboxylated cellulose nanofiber (CCNF) on the firefighting foam stability and stabilization mechanism is investigated. The results show that equilibrium surface tension of CTAB/FC1157 solution decreases when CCNF concentration increases to 0.5 wt%, while CCNF has little effect on that of SDS/FC1157 solution. Besides, when CCNF concentration increases to 1.0 wt%, the foam initial drainage of SDS/FC1157 solution is delayed for about 3 min. Increasing CCNF concentration can slow down foam coarsening process and liquid drainage process of SDS/FC1157 and CTAB/FC1157 solutions, improving the foam stability. The foam stability enhancement of CTAB/FC1157-CCNF solution is due to the formation of bulk aggregates and the increase of viscosity. However, the foam stability enhancement of SDS/FC1157-CCNF solution may be caused by the increase of viscosity. CCNF significantly reduces the foaming ability of CTAB/FC1157 solution when CCNF concentration is >0.5 wt%. Nevertheless, the foaming ability of SDS/FC1157 solution decreases significantly when CCNF concentration reaches 3.0 wt%, and its foaming ability remains higher than CTAB/FC1157 solution. The foaming ability of SDS/FC1157-CCNF solution is mainly dominated by viscosity, while that of CTAB/FC1157-CCNF solution is dominated by viscosity and adsorption kinetics . Adding CCNF is expected to enhance the stability of firefighting foam and increase the efficiency of extinguishing fire.
危险品化学品经营许可证（带存储）