Kun Liu,Yujing Ling,Xianglong Guan,Ke Hu,Angli Zhang,Kaiqi Liu,Haoyi Li,Guangnian Xu,Xu-Cheng Fu
The commercialization of magnesia-air batteries (Mg-air) necessitates the development of highly efficient, cost-effective, and durable electrocatalysts for oxygen reduction reaction (ORR), replacing expensive and unstable precious metal electrocatalysts. A hard template-assisted synthesis of FeCo nanoparticles immobilized on N-doped porous carbon (Fe-Co-C-N) for the ORR is reported. The half-wave potential of Fe-Co-C-N for ORR (E1/2=0.88 V vs. RHE) is elevated by 40 mV compared to that of 20 wt% Pt/C (E1/2=0.84 vs. RHE). The catalyst exhibits exceptional catalytic performance and remarkable stability. The discharge voltage of the Mg-air battery, utilizing Fe-Co-C-N as the cathode catalyst (1.29 V), surpasses that of the battery employing 20 wt% Pt/C as the cathode catalyst (1.28 V). The Mg-air battery with Fe-Co-C-N as the cathode catalyst exhibited excellent discharge stability and maintained a stable discharge for over 200 hours. The present study offers valuable insights into the structural design and regulatory mechanisms governing the performance of M-N-C catalysts in Mg-air batteries.
Microbial fuel cells (MFCs) systems are up-and-coming technologies for renewable energy production and wastewater treatment simultaneously. However, the inactive oxygen reduction reaction (ORR) on the cathode markedly limits the functioning of MFCs. Therefore, the cathodic catalyst is one of the crucial components in MFCs, this paper presents the removal of the antibiotic sulfamethoxazole (SMX) from water using single-chamber MFCs with Fe-Co-C/N as electrocatalysis. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS) were conducted to illustrate the structure and elemental composition of Fe-Co-C/N. The results obtained by the rotating disk electrode (RDE) method showed an extraordinary electrocatalytic activity of Fe-Co-C/N towards ORR in O 2 -saturated 0.1 M KOH. Furthermore, the degradation of SMX by MFCs that applied modified electrodes was also studied. The results demonstrated that using Fe-Co-C/N as air–cathode catalysts exhibited the degradation efficiency of 61.64% towards 6 mg/L SMX with 48 h. In addition, cyclic voltammetry (CV) analysis showed that the peak current of the biofilm in the PBS solution (without adding SMX) was significantly higher than that of the solution with SMX addition at 6, 18, and 30 mg/L. Moreover, MFC performance was also evaluated by measuring electrochemical impedance spectroscopy (EIS), power generation, and polarization curves. Last but not least, the high-throughput sequencing-based metagenomic technique was used to explore the microbial community diversity, functional genes in MFCs, and fate of ARGs. SMX addition raised the abundances of sul1 and sul2 as resistance genes, which enhanced microbial resistance, the coping capability of SMX toxicity, and the adjustment of the damage from SMX. The obtained results suggest that Fe-Co-C/N is a feasible catalyst for MFC cathodes owing to its satisfactory performance in terms of SMX wastewater treatment and power production.
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