Journal of Applied Spectroscopy
·
2023
·Vol. 90
·期 3
·670-675
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IF 0.7
Yan Kexin,Li Jinlan,Zheng Yuansong,Yan Zihong
Carbon dots (CDs) are of great significance for metal ion detection. Herein, CDs without surface functional groups were synthesized through a simple one-step hydrothermal method using 4,4'-bipyridine as the carbon source. The results showed that the synthesized CDs have good selectivity for Fe 3+ detection, and the CDs respond well to metal ions as Lewis bases. This detection method is unlikely to be affected by sewage systems because it has excellent sensitivity. The detection range for Fe 3+ concentrations is between 1.0 × 10 –8 and 1.0 × 10 2 mol/L, and the detection limit is 1.0 × 10 –8 mol/L.
研究领域:
分析化学
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环境科学
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DOI
高影响因子
EUROPEAN POLYMER JOURNAL
·
2021
·
IF 4.598
Suyan He,Li Xiao,Luminita Marin,Yike Bai,Xinjian Cheng
The development of water-soluble polymer dyes is of great practical and scientific significance. In this article, small fluorescent molecule boron-dipyrromethene (BODIPY) bearing C=C bond was synthesized first. And then, via Suzuki reaction, recognition groups were introduced into the 2, 6 positions of BODIPY. Thus polymerizable fluorescent monomers were prepared. Finally, methacrylic acid (MAA) was copolymerized with the as-prepared small molecular fluorescent monomers via reversible addition-fragmentation chain transfer (RAFT) polymerization methodology. Four fully-water-soluble polymer sensors with BODIPY moieties in the end of the polymer chain were obtained eventually. In the presence of long PMAA chain, and by the assistance of it, BODIPY could be dissolved totally in water. These polymer sensors exhibited sensitive and selective recognition ability to Fe 3+ . Even the content rate of BODIPY was as low as 0.5% of the polymer (calculated from element analysis), the detection limit could reach 1.2 μM. The sensors with two recognition groups in one BODIPY unit were more sensitive than that with one recognition groups in each BODIPY unit. The sensing mechanism was investigated as well. By endowing the water solubility to organic sensors, the application scope could be greatly enlarged in sensing metal ions in aqueous environments. This work provides a method to develop water soluble high performance polymer sensors.
研究领域:
材料科学
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化学传感器
·
分析化学
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产品关联
DOI
高影响因子
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY
·
2018
·Vol. 18
·期 6
·4196-4203
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IF 1.354
Wu Jinzhu,Feng Yaxiu,Shao Yanbin,Sun Yanchun
Nitrogen and silicon co-doped carbon nanodots (N/Si-CDs) were synthesized by one-step hydrothermal carbonization of folic acid and 3-aminopropyl trimethoxy silane with the assistance of glycerol. The resultant N/Si-CDs present intense excitation-independent photoluminescence (PL) emission
owing to their monodisperse sizes and specific surface states. In comparison to nitrogen single doped CDs (N-CDs), the co-doped N/Si-CDs possess better PL properties following different emission manner due to the synergistic effects of the nitrogen and silicon dopants. Besides, the functionalized
surfaces of N/Si-CDs endow them with superior solubility and stability. The as-synthesized N/Si-CDs demonstrate selective and sensitive fluorescence response to Fe3+, which could be explained by the PL quenching effects of Fe3+ on N/Si-CDs. Based on this finding, the
quantitative analysis of aqueous Fe3+ by N/Si-CDs was established, showing good linearity in a range of 10 nM~45 μM and good sensitivity with a detection limit of 3.8 nM, so did for the detection of Fe3+ in fetal bovine serum (FBS) spiked samples. Therefore,
the N/Si-CDs as a novel fluorescence probe hold promising for monitoring environmental and clinical Fe3+.
研究领域:
材料科学
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分析化学
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环境科学
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医学检测
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产品关联
DOI
PubMed
高影响因子
RSC Advances
·
2020
·Vol. 10
·期 61
·36971-36979
·
IF 3.119
Hua Tian,Yongcheng Dai,Wenzhe Fu,Haifang Liu,Mengting Li,Meiyuan Lv,Xueqiong Yin
In this work, a multifunctional ratiometric fluorescence (FL) nanohybrid (CSCDs@DC) was synthesized from chitosan based carbon dots (CSCDs) and dansyl chloride (DC) at room temperature. The CSCDs@DC revealed strong FL intensity, great stability and excellent anti-photobleaching properties. Herein, CSCDs@DC was responsive to pH value in the range of 1.5–4.0 and exhibited color-switchable FL properties between acidic and alkaline environments. In addition, CSCDs@DC showed good selectivity and sensitivity towards Fe3+ ions. A good linear relationship for the Fe3+ ion detection was obtained in the range from 0 μM to 100 μM, with a detection limit of 1.23 μM. What's more, CSCDs@DC can be used as a fluorescent ink. It expressed superior optical properties after 3 months of storage or continuous exposure to UV light for 24 h. This study suggested that CSCDs@DC had potential in the detection of pH and metal ions, as well as showing promising application in the anti-counterfeiting field.
研究领域:
材料科学
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分析化学
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生物医学工程
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DOI
高影响因子
ACS Omega
·
2024
·
IF 3.7
Shiqiang Hou,Ning Lin,Yi Wang
Red-emitting fluorescent carbon dots (CDs) have garnered significant attention due to their wide-ranging applications in biological fields. However, challenges such as complex precursors, labor-intensive preparation processes, and low quantum yields have hindered their broader utilization. In this study, we developed a simple and efficient solvothermal method to synthesize fluorescent CDs with tunable emission wavelengths using aniline derivatives as precursors. The emission wavelengths of the synthesized CDs were influenced by the functional groups at the para-position of the aniline derivatives with stronger electron-donating effects leading to a red shift in emissions. Notably, bright red-emitting CDs with a quantum yield of 19.42% and excellent photobleaching resistance were obtained by using p-phenylenediamine as the sole precursor. These CDs exhibited sensitivity to Fe3+ ions, demonstrating a strong linear detection range (R2 = 0.999) from 0 to 50 μM. Additionally, the CDs were uniform in size (2–5 nm), emitted stable red fluorescence in pH conditions ranging from 4 to 10, and were successfully internalized by glioma cells, enabling precise fluorescence imaging of gliomas both in vitro and in vivo.
研究领域:
生物医学工程
·
材料科学
·
肿瘤学
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产品关联
DOI
PubMed
高影响因子
Nanoscale Research Letters
·
2016
·Vol. 11
·期 1
·1-9
·
IF 2.584
Sun Chun,Zhang Yu,Wang Peng,Yang Yue,Wang Yu,Xu Jian,Wang Yiding,Yu William W.
Garlic was used as a green source to synthesize carbon dots (CDs) with a systematic study of the optical and structure properties. Ethylenediamine was added into the synthesis to improve the photoluminescence quantum yield (PL QY) of the CDs. Detailed structural and composition studies demonstrated that the content of N and the formation of C–N and C=N were critical to improve the PL QY. The as-synthesized CDs exhibited excellent stability in a wide pH range and high NaCl concentrations, rendering them applicable in complicated and harsh conditions. Quenching the fluorescence of the CDs in the presence of Fe 3+ ion made these CDs a luminescent probe for selective detection of Fe 3+ ion.
研究领域:
材料科学
·
分析化学
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产品关联
DOI
PubMed
高影响因子
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
·
2019
·
IF 2.931
Chunqing Li,Qi Sun,Qiang Zhao,Xinjian Cheng
It’s of vital importance to detect heavy metals in environment and living cells. In this work, four near-infrared regions boron dipyrromethene (BODIPY) probes (QBPH, PBPH, QBP and PBP) are constructed based on two BODIPY precursors (QB, PB) for sensing of Fe 3+ . As expected, these four probes exhibit obvious colorimetric and ratiometric response to Fe 3+ . In addition, QBP and PBP display highly sensitive and selective performance for detection of Fe 3+ . More importantly, QBP and PBP are successfully applied to near infrared imaging and detection of Fe 3+ in living A549 cells; it indicates that these novel designed probes could be a useful tool for the studies of Fe 3+ in living cells.
研究领域:
生物化学
·
分析化学
·
细胞生物学
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DOI
高影响因子
MICROCHEMICAL JOURNAL
·
2024
·
IF 4.9
Zhi-Wei Pan,Qiao-Qiao He,Ting-Ting Du,Yu-Dan Deng,QinMei Zhong,Qiang Liu,Wen-Jing Yi
Fingerprint recognition plays a crucial role due to its uniqueness. However, conventional detection methods suffer from significant drawbacks, including high consumption, health risk and sample contamination, which restrict their practical application in the crime investigations and forensic analysis. This necessitates the development of simple, rapid, safe and environmentally-friendly alternative methods for fingerprints detection. In this work, we report the synthesis of novel cyan-emitting carbon dots (CDs) via a facile one-step hydrothermal reaction using polyethyleneimine and coumarin as precursors. The CDs enabled the clear visualization of fingerprint patterns on various substrates through immersion and spraying methods with pure water solutions, without the need for any cosolvents. Level 2 and level 3 details of fingermarks were evidently visible for individual identification within a short exposure time under 365 nm UV light irradiation. Additionally, fluorescent 3D fingerprint images revealed direct and specific evidence regarding pressing habits. Interestingly, the fluorescence intensity of CDs was tunable by adjusting the pH. We further fabricated invisible CDs ink for information encryption and decryption via UV irradiation and acid/alkali treatment. Moreover, CDs have the specific ability to sense Fe 3+ ions in actual water samples, with a detection limit of 0.613 μM and a linear range of 0–27 μM. We conducted an in-depth study on the fluorescence quenching mechanism of CDs caused by Fe 3+ ions, proposing a plausible mechanism based on a synergistic effect of dynamic quenching, static quenching and inner filter effect. Therefore, this study provides a promising multifunctional nanomaterial for fingerprint recognition, data encryption, and Fe 3+ detection.
研究领域:
化学
·
纳米材料科学
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分析化学
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环境科学
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产品关联
DOI
高影响因子
RSC Advances
·
2019
·Vol. 9
·期 15
·8290-8299
·
IF 3.049
Dandan Xu,Fang Lei,Haohong Chen,Luqiao Yin,Ying Shi,Jianjun Xie
In our work, blue photoluminescent N-doped carbon dots (CDs) were developed via a green and simple hydrothermal method with citric acid and polyvinyl pyrrolidone (PVP K-30) as the carbon source and the nitrogen source, respectively. The as-prepared CDs have a high fluorescent quantum yield of 30.21% and considerable luminescence stability. The fluorescence intensity of the CDs was found to be effective quenched when adding Fe3+ ions to the CDs solution. The quenching phenomenon can be used to detect Fe3+ ions within a linear range of 0–300 μM with a detection limit of 45.5 nmol L−1, which suggested its potential application in the detection of Fe3+ ions. At the same time, we also noted the excellent self-quenching-resistant property of the as-prepared CDs in the solid state, and bright blue fluorescence was observed under UV excitation. What's more, the as-prepared CDs can also be used as fluorescent ink and were presented under UV excitation.
研究领域:
材料科学
·
分析化学
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产品关联
DOI
PubMed
高影响因子
Nanomaterials
·
2022
·Vol. 12
·期 15
·2624
·
IF 5.719
Jiayin Wu,Qilin Lu,Hanchen Wang,Biao Huang
Based on the self-passivation function of chitosan, an efficient, and green synthesis strategy was applied to prepare chitosan carbon dots (CDs). The quantum yield of carbon dots reached 35% under the conditions of hydrothermal temperature of 200 °C, hydrothermal time of 5 h, and chitosan concentration of 2%. Moreover, the obtained carbon dots had high selectivity and sensitivity to Fe3+. Based on the Schiff base reaction between the aldehyde groups of dialdehyde cellulose nanofibrils (DNF) and the amino groups of CDs, a chemically cross-linked, novel, fluorescent composite film, with high transparency and high strength, was created using one-pot processing. Knowing that the fluorescence effect of the composite film on Fe3+had a linear relationship in the concentration range of 0–100 μM, a fluorescent probe can be developed for quantitative analysis and detection of Fe3+. Owing to their excellent fluorescent and mechanical properties, the fluorescent nanocomposite films have potential applications in the fields of Fe3+detection, fluorescent labeling, and biosensing.
研究领域:
材料科学
·
生物传感
·
化学
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DOI
高影响因子
ChemistrySelect
·
2024
·Vol. 9
·期 40
·e202403099
·
IF 1.9
Jinning Dang,Yanni Li,Yujia Han,Hongxia Li,Xiaohui Niu,Deyi Zhang,Kunjie Wang
Graphical In this study, novel negatively charged carbon quantum dots(CQDs) were synthesised by a one-step hydrothermal method using tannic acid as raw material. The synthesized CQDs not only inhibit the growth of common bacteria, but also have the potential to be used as fluorescent probes for Fe 3+ with selective fluorescence bursting behaviour towards Fe 3+ . In the field of antimicrobial nanomaterials, biomass-derived carbon quantum dots have attracted great attention from contemporary researchers due to their unique physicochemical properties and favorable biosafety. In this study, novel carbon quantum dots (CQDs) were synthesized from tannic acid by a one-step hydrothermal method. The polymeric CQDs have good surface functionality and hydrophilicity with a large number of hydroxyl, carboxyl and amino functional groups. Antimicrobial experiments showed that CQDs had a good inhibitory effect on Gram-negative Escherichia coli and Gram-positive Staphylococcus aureus, as well as the drug-resistant bacterium methicillin-resistant Staphylococcus aureus. Scanning electron microscopy showed that the morphology of S.aureus cells treated with CQDs became shrivelled and irregular, the surface of E.coli cells protruded to form irregular vesicles, and the whole became shriveled up, whereas MRSA cells appeared to be depressed in the middle, and there was a residue of adherent CQDs on the cell surface. In addition, CQDs exhibit selective fluorescence bursting behavior for ferric ions and can be used as fluorescent probes for rapid, sensitive and selective detection of Fe 3+ . Therefore, CQDs not only possess good bacteriostatic properties, but also serve as fluorescent sensors for the detection of Fe 3+ . It can be used as a potential sensing array for selective detection of iron ions and bacterial abatement from contaminated water.
研究领域:
材料科学
·
微生物学
·
环境科学
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产品关联
DOI
高影响因子
POLYMERS FOR ADVANCED TECHNOLOGIES
·
2022
·Vol. 33
·期 12
·4120-4130
·
IF 3.348
Xue Meng,Da Zhang,Meng Wang,Ronghui Zhao,Pengfei Zhang,Jingyuan Zhao,Kuilin Deng
For the nontraditional aggregation-induced emission (AIE) active polymers, the heterocyclic structure on the macromolecular backbone and side chains play a crucial role in its fluorescence generation. In this paper, we facilely prepared a series of poly(β-lactam) derivatives (PLTM) by Staudinger polymerization. As expected, PLTMs with four-membered heterocycles along the main-chain shows a remarkable AIE performance with the fluorescence emission at 520 nm, while no fluorescence was observed for both β-lactam (repeating unit) and a model polymer for PLTM. The fluorescence properties of PLTMs greatly depend on the intramolecular aggregation of β-lactam structures, the size of the substituents, and appropriate length of CH 2 spacer. In addition, PLTMs can specifically detect Fe 3+ ions with a limit of detection (LOD) of 7.2 μM even in the presence of other 13 metal ions. Similar to the biological activity of β-lactam, AIE-active PLTMs shows a bactericidal effect on Staphylococcus aureus and Escherichia coli with the minimum inhibitory concentration of about 8 and 4 mg/mL. In brief, the preparation and versatility of PLTMs with β-lactam structure provide useful references for designing other nontraditional AIE-active polymers as well as for ion detection and antibacterial processes.
研究领域:
高分子化学
·
分析化学
·
生物化学
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DOI
高影响因子
危险品化学品经营许可证（带存储）