Active magnetic Fe3+-doped BiOBr micromotors as efficient solar photo-fenton catalyst
The development of new nanomaterials for the highly efficient wastewater treatment has been one of the hot scientific researches. Herein, we report a novel 3D Fe 3+ -doped BiOBr-based magnetic Janus micromotors with superior solar photo-Fenton catalytic activity for organic pollutant degradation. Taking advantage of hydrogen peroxide as reagent and fuel, Fe 3+ -doped BiOBr based Janus micromotors exhibited extremely high efficiency for methylene blue degradation in a solar photo-Fenton system even at mild pH conditions , which was almost 4 times than BiOBr. The speed of the Janus micromotors could reach 214.7 ± 19.4 μm s −1 in a 5% H 2 O 2 solution. Factors influencing the solar photo-Fenton reaction including Fe 3+ -doping amount, pH, concentration of H 2 O 2 , self-propelled movement as well as mechanical stirring were investigated to clarify the degradation mechanism . Nearly 97% of methylene blue was degraded by Fe 0.11 Bi 0.89 OBr/Fe 3 O 4 /Mn 3 O 4 Janus micromotors in the presence of 3% H 2 O 2 solution at neutral environment within 50 min. This study provided a new insight into the preparation of Janus micromotors for water purification applications based on solar photo-Fenton reaction.
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