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Fe3O4@SiO2@MnO2
CERAMICS INTERNATIONAL · 2020 · IF 3.83

Optimizing the electromagnetic wave absorption performances of designed Fe3O4@SiO2@MnO2 hybrids

Jianwen Ge,Li Liu,Yu Cui,Rui Li,Fandi Meng,Fuhui Wang

Whereas growing numbers of strong-absorption materials have been synthesized in recent years, it is also necessary to design broad-bandwidth, low-thickness, high-intensity absorbers. The ternary Fe 3 O 4 @SiO 2 @MnO 2 hybrids were fabricated via hydrothermal and hydrolysis processes, combined with typical core-shell structure characteristics and heterogeneous properties, further generating interfacial polarization behavior and enhancing anisotropy. Investigations of micromorphology manifested the hierarchical characteristic via the presence of inner mesoporous Fe 3 O 4 cores, outer SiO 2 layers (approximately 10 nm) and MnO 2 nanosheets as the surface of the hybrids. On the basis of rational design, the optimized multi-layers absorber exhibited excellent absorption performance with optimal reflection loss (RL min ) of −50.2 dB at 13.9 GHz, and the effective absorption band (EAB) is up to 5.1 GHz from 11.5 GHz to 16.6 GHz with the thickness of 2.6 mm. Due to the large surfaces, high porosity as well as the synergistic effect derived from the magnetic Fe 3 O 4 cores and dielectric SiO 2 @MnO 2 layers, this effective strategy may be endowed with high potential to design high-efficient absorbers.

研究领域: 材料科学 · 电磁学
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APPLIED SURFACE SCIENCE · 2021 · IF 6.707

Construction of silver nanoparticles anchored flower-like magnetic Fe3O4@SiO2@MnO2 hybrids with antibacterial and wound healing activity

Hang Jia,Xiao Zhang,Xuejun Zeng,Rui Cai,Zhouli Wang,Yahong Yuan,Tianli Yue

With the increased risk of wound infection caused by pathogenic bacteria, silver nanoparticles have been considered as potential antibacterial nanosystem. However, the challenge of size control and agglomeration of silver nanoparticles need to be considered. Herein, the application of flower-like silver nanoparticles (Ag NPs) anchored Fe 3 O 4 @SiO 2 @MnO 2 hybrids (Ag/FSM) in the control of pathogenic bacteria and promotion of wound healing were reported. TEM results indicated the ultrafine Ag NPs were uniformly dispersed onto the surface of FSM. In vitro experimental results showed the Minimum inhibitory concentration (MIC) of Ag/FSM against Escherichia coli ( E. coli ) and Staphylococcus aureus ( S. aureus ) were 60 and 100 μ g mL −1 , respectively. Furthermore, in vivo investigation in mice demonstrated that the hybrids showed low toxicity and effectively promoted wound healing caused by the infection of E. coli . In summary, the results supported the possibility that Ag/FSM could be considered as an antibacterial agent with potential for the treatment of bacterial infections.

研究领域: 材料科学 · 生物学 · 医学
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JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY · 2021 ·Vol. 329 ·期 1 ·253-263 · IF 1.371

Preparation of Fe3O4@SiO2@MnO2 microspheres as an adsorbent for Th(IV) removal from aqueous solution

Zhou Weini,Wang Hongqing,Hou Sanying,Wang Shiyv

A magnetic nano-composites Fe 3 O 4 @SiO 2 @MnO 2 were fabricated for efficient removal of Th(IV) from aqueous solutions, and characterized by SEM, TEM, XRD, FT-IR, BET, VSM, TGA and XPS. And the sorption of Th(IV) on Fe 3 O 4 @SiO 2 @MnO 2 were investigated as a function of pH, adsorbent dosage and initial Th(IV) concentration. The results showed that the adsorption maximum was 53.19 mg g −1 for Th(IV) at pH = 3.5 and T  = 298 K. In addition, the adsorption kinetics followed the second-order kinetic model, and the adsorption isotherm could be perfectly depicted by the Langmuir model. Finally, XPS analysis illustrated that the lattice oxygen (M–O) and the surface hydroxyl oxygen (M–OH) participated in adsorption. In brief, the Fe 3 O 4 @SiO 2 @MnO 2 material could efficiently eliminate Th(IV) from aqueous solutions, which might become a promising material for adsorbing Th(IV) from environmental wastewater.

研究领域: 环境科学 · 材料科学
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JOURNAL OF ALLOYS AND COMPOUNDS · 2020 · IF 4.65

Photocatalytic degradation of MB dye by the magnetically separable 3D flower-like Fe3O4/SiO2/MnO2/BiOBr-Bi photocatalyst

Mingliang Ma,Yuying Yang,Yan Chen,Yong Ma,Ping Lyu,Aiqi Cui,Weibo Huang,Zhe Zhang,Yanzheng Li,Feiyan Si

The flower-like Fe 3 O 4 /SiO 2 /MnO 2 /BiOBr-Bi magnetic composite photocatalyst was prepared in this work. The combination of BiOBr and Bi metal with flower-like MnO 2 constituted a heterojunction structure, which increased the specific surface area of the photocatalyst and promoted the separation of photo-generated carriers, resulting in the enhanced catalytic performance. The morphologies and the compositions of the photocatalyst were characterized in detail. Under simulated light, the degradation of organic dye methylene blue (MB) was used to research the photocatalytic activity. In the case of 15 mg photocatalyst, it was found that the photocatalytic degradation efficiency to the MB solution was 95.23% within 150 min. Moreover, the degradation rate of MB could still reach 81.11% after four cycles. The design of flower-like composites with magnetic core-shell structure provided a new method for fabricating photocatalysts having excellent catalytic performance and cyclic stability.

研究领域: 材料科学 · 环境科学
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