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Fe_x_Ni_y_OOH
IONICS · 2019 ·Vol. 26 ·期 1 ·301-309 · IF 2.289

FexNiyOOH/etched stainless steel mesh with different morphology for water electrolysis

Peng Canwei,Huang Run,Pan Guangxing,Liu Wenbin,Wang Li

Water electrolysis was recognized as an effective method for new energy sources. In this work, an effective Fe x Ni y OOH/ESS with high surface area and good catalytic activity was prepared for water electrolysis. Its morphologies at different ratio of Fe/Ni atoms were diverse, such as flower ball, flake, and block, etc. Test results showed that at 10 mA cm −2 and 300 mA cm −2 , the hydrogen evolution overpotentials of Fe 1.5 Ni 0.5 OOH/ESS were 172 mV and 258 mV. The oxygen evolution overpotentials of Fe 0.2 Ni 1.8 OOH/ESS were 208 mV and 308 mV at 10 mA cm −2 and 600 mA cm −2 . During the 136-h stability test, the oxygen evolution activity of Fe 0.2 Ni 1.8 OOH/ESS was basically unchanged. The Fe 1.5 Ni 0.5 OOH//Fe 0.2 Ni 1.8 OOH in alkaline conditions presented good performance for water electrolysis. Water electrolysis experiment was carried out at 1.58 V, and the current density reached to 10 mA cm −2 . Fe x Ni y OOH/ESS exhibited higher electrocatalytic activity and superior stability at high current density.

研究领域: 材料科学 · 电化学 · 可再生能源
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