Long Chen,Yang Wu,Heyong Huo,Bin Tang,Xiaotong Ma,Jingjing Wang,Chenghua Sun,Jibin Sun,Shuyun Zhou
Cold neutron has a strong ability to penetrate metal materials and identify light elements, making it an ideal nondestructive testing technique for detecting cracks, bubbles, or other defects in metals. However, the low imaging resolution and detection efficiency of scintillators limit the application of cold neutron technology in imaging. The particle size and luminescence properties of scintillator materials have an important influence on the spatial resolution and detection efficiency of cold neutron radiography. Here, we report a series of NaF-doped Gd2O2S:Tb3+ (NaF-d-GOS:Tb) scintillators with adjustable particle size, which were prepared through a two-step method of solution precipitation followed by solid-phase vulcanization calcination. It was found that the NaF-d-GOS:Tb scintillators showed the highest quantum yield, reaching up to 62.94%. They were applied to fabricating cold neutron ultrathin screens. The resolution can reach 12 μm in the cold neutron imaging system. These NaF-d-GOS:Tb scintillators with excellent fluorescence facilitate the development of nondestructive testing techniques based on cold neutron imaging.
Bin Tang,Wei Yin,Qibiao Wang,Long Chen,Heyong Huo,Yang Wu,Hongchao Yang,Chenghua Sun,Shuyun Zhou
High-resolution neutron radiography provides novel and stirring opportunities to investigate the structures of light elements encased by heavy elements. For this study, a series of Gd2O2S:Tb, F particles were prepared using a high-temperature solid phase method and then used as a scintillation screen. Upon reaching 293 nm excitation, a bright green emission originated from the Tb3+luminescence center. The level of F doping affected the fluorescence intensity. When the F doping level was 8 mol%, the fluorescence intensity was at its highest. The absolute quantum yield of the synthesized particles reached as high as 77.21%. Gd2O2S:Tb, F particles were applied to the scintillation screen, showing a resolution on the neutron radiograph as high as 12 μm. These results suggest that the highly efficient Gd2O2S:Tb, F particles are promising scintillators for the purposes of cold neutron radiography.
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