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Journal of Coatings Technology and Research · 2023 ·Vol. 20 ·期 5 ·1529-1539 · IF 2.3

Synthesis and performance investigation of carbon black hyperdispersant IMD

Jiang Shuangshuang,Bai Jue,Ying Xiaogang,Han Jianlin,Zhu Kai,Mao Lianshan

An aqueous dispersion of carbon black is crucial in industrial coatings. In this manuscript, a hyperdispersant IBOMA-MPEGA-DMAM (IMD) has been synthesized using isobornyl methacrylate (IBOMA), polyethylene glycol monomethyl ether acrylate (MPEGA), and N, N -dimethyl acrylamide (DMAM) as monomers via a free radical polymerization method, which is used to improve the dispersibility of an aqueous dispersion system of carbon black. The molecular structure and performance stability of IMD were investigated through comprehensive characterizations of FTIR, GPC, particle size distribution and TEM. When the molar ratio of the monomers IBOMA:MEPGA:DMAM is 5.5:8.3:9.7, the obtained hyperdispersant shows good dispersibility. When the optimal dosage of dispersant IMD was 8%, the viscosity of carbon black slurry was as low as 18.6 mPa·s and the average particle size of carbon black was 275 nm. Furthermore, the stability of the prepared carbon black slurry was better than that of the two commercial dispersants.

研究领域: 材料科学 · 化学工程
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JOURNAL OF APPLIED POLYMER SCIENCE · 2015 ·Vol. 133 ·期 3 · IF 1.768

Polyacrylate emulsion containing IBOMA for removable pressure sensitive adhesives

Lei Zhang,Yingjie Cao,Lei Wang,Lu Shao,Yongping Bai

In the area of pressure sensitive adhesives (PSAs), corona treatment or other preprocessing on the carrier was commonly utilized for the enhancement of the interaction between the adhesive layer and the carrier, with complicated procedures and operations. To make it easy, one-pot emulsion polymerization using n-butyl acrylate, isobornyl methacrylate (IBOMA), 2-hydroxyethyl acrylate and acrylic acid was conducted in the presence of a reactive emulsifier SR-20 to obtain a reinforced adhesive tape. First, the emulsion had good stabilities, especially freeze-thaw stability, which was helpful to the fabrication of PSAs. Second, IBOMA increased the binding strength between adhesive layer and adherend. The properties of the final tapes well fulfilled the requirements of this areas, such as that the 180° peel strength of 125.9 N/m when coated on non-corona surfaces, the tack of 19 #, and the shear holding time of more than 100 h. Third, the tapes produced using the above emulsion could be removed many times, with no PSAs residue on the adherend even when coated on untreated PP, which showed the potential of recycling and environmental protection. Thus, these properties make the polyacrylate emulsion have great potential for practical applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42886.

CAS / MDL: 7534-94-3
研究领域: 材料科学 · 高分子化学 · 胶粘技术
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