Solvent-Free Synthesis of ITQ-12, ITQ-13, and ITQ-17 Zeolites
Development of the sustainable routes for synthesis of ITQ-family zeolites is very important because of their unique structures and excellent catalytic and adsorptive properties. The burden of costly raw materials and low efficiency of synthesis put a strong challenge for their widespread commercial application. Here, we show an alternative and simple route for synthesis of ITQ-12, ITQ-13, and ITQ-17 zeolites using commercially available organic templates by a facile grinding process of anhydrous starting raw solids, followed by heating at 140—180 °C. Compared with the conventional hydrothermal synthesis, this approach has obvious advantages such as employment of low-cost organic templates with very high effectiveness, high yield of zeolite products, short crystallization time, and relatively simple procedures. This methodology might open a pathway to synthesize ITQ zeolites with more sustainable manner.
危险品化学品经营许可证（带存储）