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Russian Journal of Physical Chemistry A · 2018 ·Vol. 92 ·期 6 ·1224-1228 · IF 0.549

Blocking the Formation of Zn2+/Dye Complexes in Dye-Sensitized Solar Cells by Inserting CdS Quantum Dots into Sandwich Layer

Sun Yunfei,Liu Chunling,Yang Lili,Wei Maobin,Lv Shiquan,Sui Yingrui,Cao Jian,Chen Gang,Yang Jinghai

ZnO NRAs are grown on ITO substrates by a simple chemical method. CdS QDs were deposited on ZnO NRAs by SILAR. N719 was synthesized by dipping method. J–V analysis indicates that by inserting a layer of CdS QDs, the conversion efficiency of DSSCs was improved obviously. The device with CdS QDs shows the higher conversion efficiency due to the three reasons: (1) CdS QDs enhanced adsorption spectra of DSSCs in the visible region; (2) CdS QDs block the formation of Zn 2+ /dye complex, it is beneficial for electros transport from dye to ZnO photoanode. It is the key to obtain higher conversion efficiency; (3) FRET dynamics exists by the introduction of CdS QDs.

CAS / MDL: 7553-56-2 10377-51-2
研究领域: 材料科学 · 太阳能 · 纳米技术 · 光化学
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