This study explores the impact of the electroplating additive JGB the surface characteristics and peel strength of electrolytic copper foils used in printed circuit boards . Utilizing Scanning Electron Microscopy and Atomic Force Microscopy , we found that optimal JGB concentrations enhance the morphology and roughness of the copper foil roughening layer while maintaining high peel strength. The ideal concentration of 3 mg/L achieved an average roughness of 0.953 µm and a peel strength of 0.946 N/mm. JGB's effectiveness in inhibiting copper deposition was confirmed through cyclic voltammetry , linear sweep voltammetry, and electrochemical impedance spectroscopy . Density Functional Theory calculations and in situ infrared spectroscopy elucidated JGB's adsorption and coordination actions, which have a synergistic effect on its inhibitory performance. Further investigations with molecular dynamics simulations and finite element analysis demonstrated JGB's preferential adsorption in areas of high electric field intensity, effectively controlling the copper grain morphology in the roughening layer. This research highlights the potential of dye-type additives in improving copper foil roughening for printed circuit boards applications. Future research should explore the long-term stability and environmental impact of JGB in industrial applications, while investigating other dye-type additives may further optimize the roughening process to meet diverse printed circuit boards manufacturing needs.
Zhen Cheng,Fang Zhang,Xianping Chen,Lingling Du,Chutong Gao,Kejun Tan
A simple, highly sensitive and selective assay method has been developed for the determination of perfluorooctane sulfonate (PFOS), a kind of emerging persistent organic pollutant, which is bio-accumulative, resistant to degradation and toxic. It was found that PFOS can form complexes with protonated Janus Green B (JGB) through electrostatic interaction in pH 5.8 citric acid–sodium citrate (CA–NaCA) buffer medium resulting in a remarkable enhancement of the resonance light scattering (RLS) intensity of the system. The study shows that the maximum scattering wavelength is located at 319.0 nm and the enhanced RLS intensities are in proportion to the concentration of PFOS in the range of 0.05–9.0 μmol L−1 (R2 = 0.9958), with a detection limit of 5.6 nmol L−1 (3σ). Under the same experimental conditions, various perfluorinated compounds (PFPrA, PFBA, PFPeA, PFHeA, PFHpA, PFOA, PFNA, and PFBS) and JGB interactions were studied and the scattering signal changes very little. Based on the above discussion, a simple, highly sensitive and selective resonance light scattering analysis method was established for the detection of PFOS. In this work, the optimum reaction conditions were investigated. The reaction mechanism between JGB and PFOS was also studied by the absorption spectrum, scanning electron microscopy (SEM), the combination ratio and so on. This method is successfully applied to the selective detection of PFOS in environmental water samples with RSD ≤2.7%.
危险品化学品经营许可证（带存储）