Combination of Phosphoric Acid Extractants P507, P204, or Cyanex272 with LIX984 for Accelerated Extraction of Nickel in Spent Electroless Nickel Plating Baths
Hydroxamic acid extractants, such as LIX984, demonstrate high efficiency in extracting nickel from electron-free nickel waste solutions; however, they suffer from a slow extraction rate. This study investigated the effect of adding 2–5 vol.% of three organophosphate extractants (P507, P204, and Cyanex272) to LIX984. The results show that incorporating 2–5 vol.% of P507 or Cyanex272 significantly improves both extraction efficiency and kinetics. The addition of organophosphate extractants increased the extraction rate by 1.5–10 times, indicating a direct correlation between the extractant content and the acceleration of the extraction process, with higher concentrations yielding faster extraction. Compared to the use of LIX984 alone, where nickel extraction efficiency was only 46%, the addition of 5 vol.% P507 increased efficiency to over 99%, with a substantial improvement in extraction rate. Similarly, 2 vol.% P204 achieved a nickel removal efficiency of 99.8%. In non-electroplating waste solutions (pH 4–6), selective removal of iron and zinc impurities was achieved by first adding 2–5 vol.% P204 or P507, followed by adjusting the pH to 6–7 and using a mixture of organophosphate extractants. The spent electroless nickel plating baths were then treated with LIX984 combined with organophosphoric acid extractants, yielding nickel salt solutions of higher purity. Thus, P507, P204, and Cyanex272 serve as effective promoters for the hydroxamic acid extractant LIX984, resulting in both enhanced nickel extraction efficiency and faster extraction kinetics.
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