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LLTO/C复合材料
DALTON TRANSACTIONS · 2022 ·Vol. 51 ·期 18 ·7076-7083 · IF 4.569

Two-dimensional layered lithium lanthanum titanium oxide/graphene-like composites as electrodes for lithium-ion batteries

Bo Gu,Chenyang Zhan,Bing Heng Liu,Gang Wang,Qian Zhang,Ming Zhang,Zhongrong Shen

Perovskite-structured (ABO3) lithium lanthanum titanate (LixLa(2−x)/3TiO3, LLTO) is widely used in all solid state lithium ion batteries due to its high ionic conductivity. In this study, a two-dimensional LLTO nanosheet/graphene (LLTO/C) nanosheet composite has been designed as an electrode material for lithium-ion batteries (LIBs). LLTO/C not only exhibits the ionic conductivity properties of perovskite-type LLTO, but the graphene between the layers of LLTO nanosheets also endows the material with additional electronic conductivity. Moreover, LLTO@C-600 exhibits an excellent rate capability as the electrode for delithiation with a high specific capacity of 350 mA h g−1 at 20 mA g−1, and 70% of the specific capacity can be maintained at 1.0 A g−1 after 800 cycles. The excellent electrochemical performances can be attributed to the superior interficial capacitive Li+ storage capability.

研究领域: 材料科学 · 能源存储技术
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