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LNO电极
SOLID STATE COMMUNICATIONS · 2015 · IF 1.897

Effect of bottom electrodes on polarization switching and energy storage properties in Pb0.97La0.02(Zr0.95Ti0.05)O3 antiferroelectric thin films

X.G. Fang,S.X. Lin,A.H. Zhang,X.B. Lu,X.S. Gao,M. Zeng,J.-M. Liu

Polarization switching and energy storage properties of a series of Pb 0.97 La 0.02 Zr 0.95 Ti 0.05 O 3 (PLZT) thin films deposited on (100)-textured LaNiO 3 (LNO)-buffered Si substrates and (111)-textured Pt/Ti/SiO 2 /Si substrates were investigated. It was revealed that the PLZT films deposited on the (100)-textured LNO-buffered Si substrates prefer the (100) textured structure, while the orientation of the films deposited on the (111)-textured Pt-coated Si substrates is random. With respect to the films on the Pt-coated Si substrates, the (100) textured PLZT films have bigger compressive residual stress, larger electrical polarization, better dielectric properties , and better energy storage performances. For the (100)-orientated PLZT films, the energy density ( W s ) and efficiency ( η ) measured at room temperature are about 15.3   J/cm 3 and 56% respectively. Moreover, the better frequency stability in the range from 20   Hz to 10   kHz, and temperature stability in the range from 25 to 270   °C are demonstrated in the (100)-orientated PLZT films. These results indicate that the PLZT films with LNO bottom electrode could be potential candidate for applications in high energy storage density capacitors.

研究领域: 材料科学 · 物理学
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